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| | Borane-trimethylamine complex Basic information |
| | Borane-trimethylamine complex Chemical Properties |
| Hazard Codes | F,Xn,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 14-16-26-36-36/37/39-33-39 | | RIDADR | UN 1325 4.1/PG 2 | | WGK Germany | 3 | | RTECS | PA0525000 | | F | 10-21 | | TSCA | TSCA listed | | HazardClass | 4.1 | | PackingGroup | II | | HS Code | 29420000 | | Storage Class | 4.1B - Flammable solid hazardous materials | | Hazard Classifications | Eye Irrit. 2
Flam. Sol. 1
Skin Irrit. 2
STOT SE 3 |
| | Borane-trimethylamine complex Usage And Synthesis |
| Chemical Properties | white crystalline powder | | Uses | Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal. | | reaction suitability | reagent type: reductant | | Purification Methods | It is sublimed using equipment described in Burg and Schlesinger [J Am Chem Soc 59 780 1937I]. Its vapour pressure is 86mm at 100o. It forms colourless hexagonal crystals varying from needles to short lumps, which are slightly soluble in H2O (1.48% at 30o), EtOH (1%), hexane (0.74%) but very soluble in Et2O, *C6H6 and AcOH. It is stable at 125o. [Burg & Schlesinger J Am Chem Soc 59 780 1937, Brown et al. J Am Chem Soc 104 325 1942, Beilstein 4 IV 140.] |
| | Borane-trimethylamine complex Preparation Products And Raw materials |
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