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| | 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE Basic information |
| Product Name: | 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE | | Synonyms: | (Trifluoroethyl 2,2,2-trifluoroacetate);aceticacid,trifluoro-,2,2,2-trifluoroethylester;CF3C(O)OCH2CF3;ethanol,2,2,2-trifluoro-,trifluoroacetate;Trifluoroacetic acid trifluoroethyl ester;TRIFLUOROACETIC ACID 2,2,2-TRIFLUOROETHYL ESTER;2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE;Trifluoroethyl trifluoroacetate. | | CAS: | 407-38-5 | | MF: | C4H2F6O2 | | MW: | 196.05 | | EINECS: | 206-985-5 | | Product Categories: | Building Blocks;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;C2 to C5;Carbonyl Compounds;Esters | | Mol File: | 407-38-5.mol |  |
| | 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE Chemical Properties |
| Melting point | -65 °C | | Boiling point | 55 °C(lit.) | | density | 1.464 g/mL at 25 °C(lit.) | | vapor pressure | 3.34 psi ( 20 °C) | | refractive index | n20/D 1.277(lit.) | | Fp | 32 °F | | storage temp. | Flammables area | | solubility | soluble in Chloroform | | form | clear liquid | | color | Colorless to Almost colorless | | Specific Gravity | 1.464 | | BRN | 1783427 | | InChI | InChI=1S/C4H2F6O2/c5-3(6,7)1-12-2(11)4(8,9)10/h1H2 | | InChIKey | ZKUJOCJJXCPCFS-UHFFFAOYSA-N | | SMILES | C(OCC(F)(F)F)(=O)C(F)(F)F | | CAS DataBase Reference | 407-38-5(CAS DataBase Reference) | | EPA Substance Registry System | 2,2,2-Trifluoroethyl 2,2,2-trifluoroacetate (407-38-5) |
| Hazard Codes | F,C | | Risk Statements | 11-34 | | Safety Statements | 16-26-27-36/37/39-45 | | RIDADR | UN 2924 3/PG 2 | | WGK Germany | 3 | | Hazard Note | Flammable/Corrosive | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29159000 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Flam. Liq. 2
Skin Corr. 1B |
| | 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS LIQUID | | Uses | 2,2,2-Trifluoroethyl trifluoroacetate has been used in the preparation of dimethyl (3,3,3-trifluoro-2,2-dihydroxypropyl)phosphonate. | | General Description | The molecular structure of 2,2,2-trifluoroethyl trifluoroacetate has been determined in the gas-phase from electron-diffraction data supplemented by ab initio (MP2) and DFT calculations. Hydrogenation of 2,2,2-trifluoroethyl trifluoroacetate catalyzed by anionic tris-phosphine ruthenium hydride complex has been reported. | | Purification Methods | 2,2,2-Trifluoroethyl trifluoroacetate is purified by distillation from calcium hydride at atmospheric pressure.
| | storage |
2,2,2-Trifluoroethyl trifluoroacetate can be adequately dried by simple distillation and can be stored under argon over 4 Angstrom molecular sieves.
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| | 2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE Preparation Products And Raw materials |
| Raw materials | 2,2,2-Trifluoroethanol-->Trifluoroacetic acid | | Preparation Products | ETHYL 2-METHYL-4,4,4-TRIFLUOROACETOACETATE-->N,N-DIETHYL-2,2,2-TRIFLUOROACETAMIDE-->4,4,4-TRIFLUORO-1-(2-FURYL)-1,3-BUTANEDIONE-->4,4,4-Trifluoro-1-(2-bromophenyl)-1,3-butanedione |
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