| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
|
| | Diethyl (2-methylallyl)phosphonate 97 Basic information |
| | Diethyl (2-methylallyl)phosphonate 97 Chemical Properties |
| Boiling point | 62 °C/0.1 mmHg (lit.) | | density | 1.013 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.4380(lit.) | | Fp | >230 °F | | InChI | 1S/C8H17O3P/c1-5-10-12(9,11-6-2)7-8(3)4/h3,5-7H2,1-2,4H3 | | InChIKey | QOZGSMHGXZMADD-UHFFFAOYSA-N | | SMILES | CCOP(=O)(CC(C)=C)OCC |
| Hazard Codes | Xi | | Risk Statements | 36 | | Safety Statements | 26 | | WGK Germany | 3 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2 |
| | Diethyl (2-methylallyl)phosphonate 97 Usage And Synthesis |
| Uses | Diethyl (2-methylallyl)phosphonate can be used as a reagent in the Horner-Wadsworth-Emmons reaction to form conjugated carbon–carbon double bonds.
It can also be used as a reactant for:
- Enantioselective total synthesis of 10-isocyano-4-cadinene as antifouling agent.
- Regiospecific preparation of 4-oxo-2-alkenylphosphonates (OAP) via silylation followed by Friedel-Crafts acylation and isomerization. OAP can serve as building blocks for the construction of polyethylenic chains.
- The synthesis of azaphosphone as a potent analgesic/anti-inflammatory agents.
| | General Description | Diethyl (2-methylallyl)phosphonate is an organophosphorous compound. It participates in the synthesis of α-aminophosphonate derivatives and azaphosphones. The analgesic/antiinflammatory properties of these derivatives were evaluated. | | reaction suitability | reaction type: C-C Bond Formation |
| | Diethyl (2-methylallyl)phosphonate 97 Preparation Products And Raw materials |
|