- (DHQD)2PHAL
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- $15.00 / 1KG
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2021-08-12
- CAS:140853-10-7
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
- (DHQD)2-PHAL
-
- $15.00 / 1KG
-
2021-07-13
- CAS:140853-10-7
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
- (DHQD)2-PHAL
-
- $15.00 / 1KG
-
2021-07-10
- CAS:140853-10-7
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
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| | (DHQD)2PHAL Basic information |
| Product Name: | (DHQD)2PHAL | | Synonyms: | SHARPLESS CATALYST;(DHQD)2PHAL;HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER;DHQD)2 PHAL;(DHQD)2 PHAL, 95+%;HYDROQUININE-1,4-PHTHALOZINEDIYL DIETHER;Hydroquinidine 1,4-phthalazinediyl diether((DHQD)2PHAL);(DHQD)2PHAL,Hydroquinidine 1,4-phthalazinediyl diether | | CAS: | 140853-10-7 | | MF: | C48H54N6O4 | | MW: | 778.98 | | EINECS: | 1308068-626-2 | | Product Categories: | | | Mol File: | 140853-10-7.mol |  |
| | (DHQD)2PHAL Chemical Properties |
| Melting point | 160 °C (dec.)(lit.) | | alpha | -262 º (C=1.2 IN MEOH) | | density | 1.3 | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly) | | form | Solid | | pka | 9.61±0.70(Predicted) | | color | White to Pale Yellow | | Optical Rotation | [α]22/D 262°, c = 1.2 in methanol | | BRN | 5475678 | | InChIKey | YUCBLVFHJWOYDN-SOBQURILSA-N | | SMILES | CC[C@H]1CN2CCC1CC2[C@@H](Oc3nnc(O[C@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c8ccccc38)c9ccnc%10ccc(OC)cc9%10 | | CAS DataBase Reference | 140853-10-7(CAS DataBase Reference) |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | F | 9 | | HS Code | 29392000 | | Storage Class | 11 - Combustible Solids |
| | (DHQD)2PHAL Usage And Synthesis |
| Uses | (DHQD)2PHAL is a monomeric cinchona alkaloid dimer used as a catalyst for asymmetric halogenations. | | Uses | (DHQD)2PHAL may be used as ligand for:
- Osmium trioxide catalyzed asymmetric dihydroxylation of olefins.
- Palladium catalyzed Suzuki-Miyaura coupling of aryl/heteroaryl halides with aryl boronic acids in aqueous medium and in the absence of phosphine/organic solvent.
- Copper(I)-catalyzed azide-alkyne cycloaddition reaction to synthesize 1,2,3-triazoles in water.
| | General Description | (DHQD)2PHAL is a modified cinchona alkaloid derivative mainly used as a ligand for enantioselective catalysis. |
| | (DHQD)2PHAL Preparation Products And Raw materials |
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