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| Product Name: | Benzoic acid, 2-(methylamino)-, ethyl ester | | Synonyms: | Ethyl 2-(methylamino);ethyl methyl anthranilate;Benzoic acid, 2-(methylamino)-, ethyl ester;ETHYLN-METHYLANTHRANILATE;2-(Methylamino)benzoic acid ethyl ester;o-(Methylamino)benzoic acid ethyl ester | | CAS: | 35472-56-1 | | MF: | C10H13NO2 | | MW: | 179.22 | | EINECS: | | | Product Categories: | | | Mol File: | 35472-56-1.mol |  |
| | Benzoic acid, 2-(methylamino)-, ethyl ester Chemical Properties |
| Melting point | 39°C | | Boiling point | 311.75°C (rough estimate) | | density | 1.1248 (rough estimate) | | refractive index | 1.5710 (estimate) | | FEMA | 4116 | ETHYL N-METHYLANTHRANILATE | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | pka | 2.77±0.10(Predicted) | | Odor | at 100.00 %. soft sweet mandarin petitgrain | | Odor Type | fruity | | JECFA Number | 1546 | | LogP | 3.22 |
| | Benzoic acid, 2-(methylamino)-, ethyl ester Usage And Synthesis |
| Aroma | Sweet and soft fruity-floral odor, reminiscent of Pctitgrain or Mandarin-petitgrain oils.
Excellent tenacity.
Grape-like (Concord type), winey and sweet
taste of considerable power. | | Uses in Perfume | Benzoic acid, 2-(methylamino)-, ethyl ester has found a little usc in perfume
compositions as a variant of the conventional
"Orangcblossom"-type of Anthranilates. It
blends excellently with the Citrus oils, in
Fougere themes, in Lavender fantasy compositions, in Magnolia and Honeysuckle and many
other heavy floral bases.
It has very little
tendency to form strong-colored condensation products with aldchydcs, except for the
fact that most "Di-anthranilates" contain a
significant proportion of the Mono-ester,
which causes strong coloration with aldehydes. | | Chemical Properties | Yellowish solid; fruity mandarin-type aroma. | | Definition | ChEBI: Ethyl N-methylanthranilate is a benzoate ester. | | Production Methods | Benzoic acid, 2-(methylamino)-, ethyl ester can be produced from N-Mcthylanthranilic acid and
Ethyl alcohol, by azcotropic type csterification; or by Methylation of Ethyl anthranilate with
Dimethyl sulfate. | | Aroma threshold values | Medium strength odor, fruity type. | | References | [1] European Journal of Medicinal Chemistry, 2015, vol. 95, p. 29 - 34
[2] Chemische Berichte, 1901, vol. 34, p. 1645
[3] Chem. Zentralbl., 1906, vol. 77, # II, p. 1007
[4] Chemische Berichte, 1920, vol. 53, p. 2354
[5] Archiv der Pharmazie (Weinheim, Germany), 1925, p. 494 |
| | Benzoic acid, 2-(methylamino)-, ethyl ester Preparation Products And Raw materials |
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