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DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE

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Products Intro: Product Name:Diethyl (2-(methoxy(methyl)amino)-2-oxoethyl)phosphonate
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DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Basic information
Product Name:DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE
Synonyms:N-METHOXY-N-METHYL-PHOSPHONOACETAMIDE DIETHYL ESTER;DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE;DIETHYL N-METHOXY-N-METHYLPHOSPHONOACETAMIDE;Diethyl(N-methoxy-N-methylcarbamoylmethyl)phosphonate, min. 97 %;(N-Methoxy-N-methylcarbamoylmethyl)phosphonic Acid Diethyl Ester;diethyl (N-ethoxy-N-methylcarbamoylmethyl)phosphonate;Diethyl N-methoxy-N-methylphosphonoacetamide, N-Methoxy-N-methyl-phosphonoacetamide diethyl ester;Diethyl (2-(Methoxy(Methyl)aMino)-2-oxoethyl)phosphonate
CAS:124931-12-0
MF:C8H18NO5P
MW:239.21
EINECS:
Product Categories:Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Horner-Emmons Reaction
Mol File:124931-12-0.mol
DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Structure
DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Chemical Properties
Boiling point 90 °C17 mm Hg(lit.)
density 1.163 g/mL at 25 °C(lit.)
refractive index n20/D 1.455(lit.)
Fp >230 °F
storage temp. Store at room temperature
form clear liquid
color Colorless to Almost colorless
BRN 1875865
InChI1S/C8H18NO5P/c1-5-13-15(11,14-6-2)7-8(10)9(3)12-4/h5-7H2,1-4H3
InChIKeyWYLRYBDGIILFIR-UHFFFAOYSA-N
SMILESCCOP(=O)(CC(=O)N(C)OC)OCC
CAS DataBase Reference124931-12-0
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29319000
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Usage And Synthesis
UsesReactant for:
  • Preparation of ring-expanded bryostatin analogs as antitumor agents
  • Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization
  • Rh2(II)-catalyzed nitro-group migration reactions
  • Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions
  • Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps
  • Preparation of substituted furans via olefin cross-metathesis
reaction suitabilityreaction type: C-C Bond Formation
Tag:DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE(124931-12-0) Related Product Information
DIETHYL (FORMYLMETHYL)PHOSPHONATE (2-Aminoethyl)phosphonic acid Phosphonic acid, (carbamoylmethyl)-, diethyl ester DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Diethyl ethoxymethylenemalonate