DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Suppliers list

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Products Intro:	Product Name:Diethyl (2-(methoxy(methyl)amino)-2-oxoethyl)phosphonate CAS:124931-12-0 Purity:NLT 98% Remarks:MC805800

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Basic information

Product Name:	DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE
Synonyms:	N-METHOXY-N-METHYL-PHOSPHONOACETAMIDE DIETHYL ESTER;DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE;DIETHYL N-METHOXY-N-METHYLPHOSPHONOACETAMIDE;Diethyl(N-methoxy-N-methylcarbamoylmethyl)phosphonate, min. 97 %;(N-Methoxy-N-methylcarbamoylmethyl)phosphonic Acid Diethyl Ester;diethyl (N-ethoxy-N-methylcarbamoylmethyl)phosphonate;Diethyl N-methoxy-N-methylphosphonoacetamide, N-Methoxy-N-methyl-phosphonoacetamide diethyl ester;Diethyl (2-(Methoxy(Methyl)aMino)-2-oxoethyl)phosphonate
CAS:	124931-12-0
MF:	C8H18NO5P
MW:	239.21
EINECS:
Product Categories:	Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Horner-Emmons Reaction
Mol File:	124931-12-0.mol

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Chemical Properties

Boiling point	90 °C17 mm Hg(lit.)
density	1.163 g/mL at 25 °C(lit.)
refractive index	n20/D 1.455(lit.)
Fp	>230 °F
storage temp.	Store at room temperature
form	clear liquid
color	Colorless to Almost colorless
BRN	1875865
InChI	1S/C8H18NO5P/c1-5-13-15(11,14-6-2)7-8(10)9(3)12-4/h5-7H2,1-4H3
InChIKey	WYLRYBDGIILFIR-UHFFFAOYSA-N
SMILES	CCOP(=O)(CC(=O)N(C)OC)OCC
CAS DataBase Reference	124931-12-0

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Usage And Synthesis

Uses

Reactant for:

Preparation of ring-expanded bryostatin analogs as antitumor agents
Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization
Rh2(II)-catalyzed nitro-group migration reactions
Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions
Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps
Preparation of substituted furans via olefin cross-metathesis

reaction suitability

reaction type: C-C Bond Formation

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials	Dichloromethane-->Triethylamine-->Triethyl phosphite-->Bromoacetyl bromide-->N,O-Dimethylhydroxylamine hydrochloride
Preparation Products	(2E)-N-methoxy-3-(2-methoxyphenyl)-N-methylprop-2-enamide-->3-(4-chlorophenyl)-N-methoxy-N-methylacrylamide-->(2E)-N-methoxy-3-(4-methoxyphenyl)-N-methylprop-2-enamide

Tag:DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE(124931-12-0) Related Product Information

DIETHYL (FORMYLMETHYL)PHOSPHONATE (2-Aminoethyl)phosphonic acid Phosphonic acid, (carbamoylmethyl)-, diethyl ester DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Diethyl ethoxymethylenemalonate

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