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| | (Trimethylsilyl)methylamine Basic information |
| Product Name: | (Trimethylsilyl)methylamine | | Synonyms: | (AMINOMETHYL)TRIMETHYLSILANE;(TRIMETHYLSILYL)METHYLAMINE;2-AMINOMETHYLTRIMETHYLSILANE;Methylamine, 1-(trimethylsilyl)-,;1-(trimethylsilyl)methylamine;Aminomethyltrimethylsilane**CUSTOMSYNTHESISPLEASEASK**;AMTMS;Trimethylsilylmethaneamine | | CAS: | 18166-02-4 | | MF: | C4H13NSi | | MW: | 103.24 | | EINECS: | 242-049-2 | | Product Categories: | | | Mol File: | 18166-02-4.mol |  |
| | (Trimethylsilyl)methylamine Chemical Properties |
| Melting point | <0°C | | Boiling point | 92-94 °C(lit.) | | density | 0.771 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.416 | | Fp | 9°C | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | liquid | | pka | 10.89±0.10(Predicted) | | Specific Gravity | 0.7697 | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 1731488 | | InChI | InChI=1S/C4H13NSi/c1-6(2,3)4-5/h4-5H2,1-3H3 | | InChIKey | YVWPNDBYAAEZBF-UHFFFAOYSA-N | | SMILES | C([Si](C)(C)C)N | | CAS DataBase Reference | 18166-02-4(CAS DataBase Reference) | | NIST Chemistry Reference | Trimethylsilylmethylamine(18166-02-4) |
| Hazard Codes | F,C | | Risk Statements | 11-34-37 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2733 3/PG 2 | | WGK Germany | 3 | | F | 3-10 | | TSCA | No | | HazardClass | 3.1 | | PackingGroup | II | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Flam. Liq. 2
Skin Corr. 1B |
| | (Trimethylsilyl)methylamine Usage And Synthesis |
| Purification Methods | A possible contaminant is hexamethyldisiloxane. It should have two 1H NMR signals in CDCl3; if not, dissolve it in *C6H6, shake it with 15% aqueous KOH, separate, dry (Na2SO4), filter, evaporate and distil it using a still of ca 10 theoretical plates. The water azeotrope has b 83o/735mm; hence it is important to dry the extract well. The hydrochloride has m 198-199o (from MeOH or Me2CO). [Noll et al. J Am Chem Soc 73 3867 1951, Beilstein 4 IV 3878.] |
| | (Trimethylsilyl)methylamine Preparation Products And Raw materials |
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