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| | TITANIUM(IV) BROMIDE Basic information |
| Product Name: | TITANIUM(IV) BROMIDE | | Synonyms: | TiBr4;Titanium bromide;Titanium bromide (TiBr4), (T-4)-;Titaniumbromide(TiBr4),(T-4)-;TITANIUM(IV) BROMIDE, ANHYDROUS, POWDER, 99.99%;TITANIUM(IV) BROMIDE;TITANIUM TETRABROMIDE;Titanium(IV)bromide,min.98% | | CAS: | 7789-68-6 | | MF: | Br4Ti | | MW: | 367.48 | | EINECS: | 232-185-0 | | Product Categories: | metal halide | | Mol File: | 7789-68-6.mol |  |
| | TITANIUM(IV) BROMIDE Chemical Properties |
| Melting point | 38-40 °C(lit.) | | Boiling point | 230 °C(lit.) | | density | 3.25 g/mL at 25 °C(lit.) | | Fp | 233°C | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | solubility | reacts with H2O | | form | powder | | Specific Gravity | 2.6 | | color | Orange | | Water Solubility | Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol. | | Sensitive | Moisture Sensitive | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | Merck | 14,9477 | | InChI | 1S/4BrH.Ti/h4*1H;/q;;;;+4/p-4 | | InChIKey | UBZYKBZMAMTNKW-UHFFFAOYSA-J | | SMILES | Br[Ti](Br)(Br)Br | | CAS DataBase Reference | 7789-68-6 |
| Hazard Codes | C | | Risk Statements | 14-34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3260 8/PG 2 | | WGK Germany | 3 | | F | 3-8-10-21 | | TSCA | No | | HazardClass | 8 | | PackingGroup | II | | HS Code | 28275900 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | TITANIUM(IV) BROMIDE Usage And Synthesis |
| Chemical Properties | Orange low melting lumps and powder | | Uses | Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates. | | reaction suitability | core: titanium
reagent type: catalyst | | Purification Methods | Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.] |
| | TITANIUM(IV) BROMIDE Preparation Products And Raw materials |
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