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Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

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Products Intro: Product Name:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
CAS:19999-87-2
Purity:0.99 Package:1g;1.00;USD
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Products Intro: Product Name:Bis(tricyclohexylphosphine)nickel(II) chloride
CAS:19999-87-2
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Products Intro: Product Name:Bis(tricyclohexylphosphine)nickel(II) Dichloride
CAS:19999-87-2
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Products Intro: Product Name:Dichlorobis(tricyclohexylphosphine)nickel(II)
CAS:19999-87-2
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Products Intro: Product Name:Bis(tricyclohexylphosphine)nickel(II)dichloride
CAS:19999-87-2
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Bis(tricyclohexylphosphine)nickel(II) chloride, 99% manufacturers
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Basic information
Reaction
Product Name:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
Synonyms:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%;Dichlorobis(tricyclohexylphosphine)nickel(II);Bis(tricyclohexylphosphine)nickel(II) Dichloride;Bis(tricyclohexylphosphine)nickel(II)chloride,99%;Bis(tricyclohexylphosphine)nickel(II) chloride,98% (PCy3)2NiCl2;Bis(tricyclohexylphosphine)dichloronickel;Dichlorobis(tricyclohexylphosphine)nickel;Bis(tricyclohexylphosphine)nickel(II) chloride,98%
CAS:19999-87-2
MF:2C18H33P.Cl2Ni
MW:690.464
EINECS:
Product Categories:Ni;metal-phosphine complexes
Mol File:19999-87-2.mol
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Structure
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Chemical Properties
Melting point 227-231℃ (DEC.)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color Yellow to Amber to Dark red
InChIInChI=1S/2C18H33P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*16-18H,1-15H2;2*1H;/q;;;;+2/p-2
InChIKeyYOCBOYPGZVFUCQ-UHFFFAOYSA-L
SMILESC1(CCCCC1)P(C1CCCCC1)C1CCCCC1.C1(CCCCC1)P(C1CCCCC1)C1CCCCC1.Cl[Ni]Cl
CAS DataBase Reference19999-87-2
Safety Information
Hazard Codes Xn
Risk Statements 22-40-43
Safety Statements 53-36/37-45-60
WGK Germany 3
HS Code 2931.90.9051
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Carc. 2
Skin Sens. 1
MSDS Information
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Usage And Synthesis
Reaction
  1. An approach to five-membered lactams from aliphatic amides and terminal acetylenes by nickel catalysis.
  2. Synthesis of biaryls through nickel-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen bond cleavage.
  3. Ni-catalyzed borylation of aryl fluorides via C-F cleavage.
  4. Nickeland palladium–catalyzed coupling of aryl fluorosulfonates with aryl boronic acids enabled by sulfuryl fluoride.
  5. Nickel-catalyzed one-pot synthesis of biaryls from phenols and arylboronic acids via C-O activation using TCT reagents.
Reactions of 19999-87-2
UsesCatalyst for:
  • Dehydrobrominative polycondensation
  • Arylation reactions
  • Cross-coupling
  • Suzuki-miyaura cross-coupling reactions
  • Kumada coupling of diaryl sulfates with Grignard reagents
  • Olefin dimerization
reaction suitabilitycore: nickel
reagent type: catalyst
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Preparation Products And Raw materials
Tag:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%(19999-87-2) Related Product Information
BIS(DITHIOBENZIL) NICKEL Bis(triphenylphosphine)nickel(II)chloride Bis(tricyclohexylphosphine)palladium(0) Bis(tricyclohexylphosphine)palladium(II) Dichloride Grubbs catalyst 2nd generation Ruthenium acetylacetonate Benzeneruthenium(II) chloride dimer [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Tris(triphenylphosphine)ruthenium(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro(p-cymene)ruthenium(II) dimer Rhodium(II) acetate dimer Ruthenium(II) chloride mesitylene dimer TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Dichloro(cycloocta-1,5-diene)ruthenium(II) Tris(triphenylphosphine)chlororhodium 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
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