β-D-Glucose pentaacetate

β-D-Glucose pentaacetate Suppliers list

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β-D-Glucose pentaacetate manufacturers

β-D-Glucose pentaacetate Basic information

Product Name:	β-D-Glucose pentaacetate
Synonyms:	Beta-Pentacetylglucose;PENTAACETYL-BETA-D-GLUCOSE;PENTA-O-ACETYL-BETA-D-GLUCOPYRANOSIDE;PENTA-O-ACETYL-BETA-D-GLUCOPYRANOSE;1,2,3,4,6-Penta-O-acetylhexopyranose;beta-D-Glucopyranosyl pentaacetate;Glucopyranose, pentaacetate, beta-D-;Pentaacetyl-beta-D-glucopyranose
CAS:	604-69-3
MF:	C16H22O11
MW:	390.34
EINECS:	210-074-8
Product Categories:	carbohydrate;Biochemistry;Glucose;O-Substituted Sugars;Sugars;Carbohydrates & Derivatives;Sugars, Carbohydrates & Glucosides;bc0001
Mol File:	604-69-3.mol

β-D-Glucose pentaacetate Chemical Properties

Melting point	130-132 °C
alpha	5 º (c=1, CHCl3)
Boiling point	435.58°C (rough estimate)
density	1,274 g/cm³
refractive index	4.5 ° (C=5, CHCl3)
storage temp.	Inert atmosphere,Room Temperature
solubility	chloroform: 0.1 g/mL, clear, colorless
form	Crystalline Powder
color	White to off-white
Odor	at 100.00%. odorless
Optical Rotation	[α]20/D +4.2°, c = 1 in chloroform
Water Solubility	Soluble in chloroform and methanol. Insoluble in water.
BRN	98851
InChI	1S/C16H22O11/c1-7(17)22-6-12-13(23-8(2)18)14(24-9(3)19)15(25-10(4)20)16(27-12)26-11(5)21/h12-16H,6H2,1-5H3/t12-,13-,14+,15-,16-/m1/s1
InChIKey	LPTITAGPBXDDGR-XJGFBQBWSA-N
SMILES	CC(O)O[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O
LogP	0.634 (est)
CAS DataBase Reference	604-69-3(CAS DataBase Reference)
NIST Chemistry Reference	Acetyl 2,3,4,6-tetra-o-acetyl-«beta»-D-glucopyranoside(604-69-3)

Safety Information

MSDS Information

β-D-Glucose pentaacetate Usage And Synthesis

Chemical Properties	white to beige powder
Uses	beta-D-Glucose pentaacetate was reported to stimulate insulin release in rat pancreatic islets.
Uses	β-D-Glucose Pentaacetate is used in biochemical reaction and also used as an active pharmaceutical intermediate. Further, it is used to stimulate insulin release in rat pancreatic islets.
Definition	ChEBI: Beta-d-glucose pentaacetate is an organooxygen compound. It is functionally related to a hexacarboxylic acid.
Purification Methods	Crystallise the pentaacetate from MeOH or EtOH. It is best purified by recrystallising 160g from 1L of hot 95% EtOH (charcoal) and filtering hot. It is important that as soon as the temperature of the filtrate cools to ~20o it is filtered off. Note that some -D-isomer will crystallise out if a prolonged crystallisation period is allowed. Further crystallisation in this manner and drying in a vacuum over CaCl2 will give pure -D-anomer which has m 132o, [] D 20 + 4o (c 5, CHCl3). [Wolfrom & Thompson Methods in Carbohydrate Chemistry II 212 1963, Academic Press, Krahl & Cori Biochemical Preparations 1 33 1955, Beilstein 17/7 V 319.]

β-D-Glucose pentaacetate Preparation Products And Raw materials

Raw materials	D-Gulopyranose-->Glucose pentaacetate-->β-D-Mannopyranose
Preparation Products	beta-D-Glucopyranosylamine-->2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL TRICHLOROACETIMIDATE-->BENZYL ALPHA-D-GLUCOPYRANOSIDE-->1-AZIDO-1-DEOXY-BETA-D-GLUCOPYRANOSIDE-->1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE-->ACETAGASTRODINE-->N-NONYL-BETA-D-GLUCOPYRANOSIDE-->ETHYLVANILLINBETA-D-GLUCOPYRANOSIDE

Tag:β-D-Glucose pentaacetate(604-69-3) Related Product Information

Amyl acetate Acetyl coenzyme A sodium salt Tocopheryl acetate D-Glucose monohydrate CORN SYRUP Linalyl acetate D(+)-Glucose Triacetin POLY(VINYL ACETATE) Acetyl chloride Acetylacetone Glucose oxidase Vinyl acetate Benzyl acetate Glucose pentaacetate Pentachlorophenol glucopyranose ALPHA, BETA-D-(+)-GLUCOSE PENTAACETATE (HIGH BETA),ALPHA, BETA-D-GLUCOSE PENTAACETATE,Beta-D-Glucose Pentaacetate 98%

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