Tributyl(2-phenylethenyl)stannane

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Tributyl(2-phenylethenyl)stannane Basic information
Product Name:Tributyl(2-phenylethenyl)stannane
Synonyms:(2-Phenylethenyl)tributylstannane;[2-(Tributylstannyl)ethenyl]benzene;1-(Tributylstannyl)-2-phenylethene;Styryltributylstannane;Tributyl(2-phenylethenyl)stannane;Tributyl(styryl)stannane;tributyl(3-phenyl-2-propen-1-yl)Stannane;Stannane, tributyl(3-phenyl-2-propen-1-yl)-
CAS:19752-27-3
MF:C21H36Sn
MW:407.22
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Mol File:19752-27-3.mol
Tributyl(2-phenylethenyl)stannane Structure
Tributyl(2-phenylethenyl)stannane Chemical Properties
Boiling point 426.8±48.0 °C(Predicted)
alpha n20D 1.5185
solubility sol THF, methylene chloride, chloroform.
Safety Information
MSDS Information
Tributyl(2-phenylethenyl)stannane Usage And Synthesis
UsesTributyl(2-phenylethenyl)stannane is a phenylallylating agent as an anion equivalent; 3-carbon component in a [3 + 2] cycloaddition reaction with α,β-unsaturated acylirons.
PreparationPreparative Methods of Tributyl(2-phenylethenyl)stannane: by the coupling reaction of trans-cinnamylmagnesium bromide with Tri-n-butylchlorostannane (10-20%) or trapping of the lithiated derivative of allylbenzene (s-BuLi in cyclohexane/TMEDA/THF) with tributylchlorostannane at -78 °C (90%).
Tributyl(2-phenylethenyl)stannane Preparation Products And Raw materials
Tag:Tributyl(2-phenylethenyl)stannane(19752-27-3) Related Product Information
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) TRI-P-TOLYLPHOSPHINE