(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole

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(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole Basic information
Product Name:(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole
Synonyms:(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole;(4R,4'R,5S,5'S)-2,2'-Cyclopropylidenebis[4,5-dihydro-4,5- diphenyloxazole],99%e.e.;(4R,4'R,5S,5'S)-2,2'-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole], 98%, (99% ee);Oxazole, 2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-, (4R,4'R,5S,5'S)- (9CI);(4R,4'R,5S,5'S)-2,2'-(Cyclopropane-1,1-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole);Oxazole, 2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-,(4R,4'R,5S,5'S)-;(4R,4''R,5S,5''S)-2,2''-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole];(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole]
CAS:229184-96-7
MF:C33H28N2O2
MW:484.6
EINECS:
Product Categories:
Mol File:229184-96-7.mol
(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole Structure
(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole Chemical Properties
Melting point 163-165 °C
Boiling point 620.8±55.0 °C(Predicted)
density 1.23±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form powder
pka4.66±0.70(Predicted)
AppearanceOff-white to light yellow Solid
InChIKeyUAXGHJCFHMQPBJ-AUJRTDPGNA-N
SMILESC1(C2O[C@@H](C3C=CC=CC=3)[C@@H](C3C=CC=CC=3)N=2)(C2O[C@@H](C3C=CC=CC=3)[C@@H](C3C=CC=CC=3)N=2)CC1 |&1:3,10,20,27,r|
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
MSDS Information
(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole Usage And Synthesis
Uses(4R,4μR,5S,5μS)-2,2μ-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole] is a bisoxazoline (BOX) ligand for asymmetric catalysis. The copper-ligand complex has been shown to catalyze reactions of symmetric diaziridines with enol diazo compounds.
(4R,4'R,5S,5'S)-2,2'-cyclopropylidenebis[4,5-dihydro-4,5-diphenyl-Oxazole Preparation Products And Raw materials
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