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6-Cyanoindole

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CAS:15861-36-6
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CAS:15861-36-6
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6-Cyanoindole manufacturers

  • 6-Cyanoindole
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  • $10.00 / 1KG
  • 2026-03-20
  • CAS:15861-36-6
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 10 mt
  • 6-Cyanoindole
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  • 2023-08-08
  • CAS:15861-36-6
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  • Purity: 99%
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  • 6-Cyanoindole
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  • $0.00 / 1KG
  • 2022-02-09
  • CAS:15861-36-6
  • Min. Order: 1KG
  • Purity: 98.8%
  • Supply Ability: 100 tons
6-Cyanoindole Basic information
Product Name:6-Cyanoindole
Synonyms:6-CYANOINDOLE;6-Cyanoindole in stock Factory;CYANOINDOLE-6;INDOLE-6-CARBONITRILE;1H-indole-6-carbonitrile;Indole-6-carbonitrile, 98+%;6-Indolecarbonitrile;6-Cyanoidole
CAS:15861-36-6
MF:C9H6N2
MW:142.16
EINECS:239-988-5
Product Categories:Indole Derivatives;blocks;Carboxes;IndolesOxindoles;Indoles and derivatives;Indole;Indoles;Simple Indoles
Mol File:15861-36-6.mol
6-Cyanoindole Structure
6-Cyanoindole Chemical Properties
Melting point 130-132°C
Boiling point 350.0±15.0 °C(Predicted)
density 1.24±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Dichloromethane, Methanol
form Solid
pka15.17±0.30(Predicted)
color Off-White Crystalline
Sensitive Air & Light Sensitive
BRN 116502
InChIInChI=1S/C9H6N2/c10-6-7-1-2-8-3-4-11-9(8)5-7/h1-5,11H
InChIKeySZSZDBFJCQKTRG-UHFFFAOYSA-N
SMILESN1C2=C(C=CC(C#N)=C2)C=C1
CAS DataBase Reference15861-36-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 22-36/37/38
Safety Statements 22-36/37-26
RIDADR 3439
HazardClass 6.1
PackingGroup III
HS Code 29339900
MSDS Information
ProviderLanguage
ALFA English
6-Cyanoindole Usage And Synthesis
Chemical PropertiesOff-White Crystalline Solid
Uses6-Cyanoindole (cas# 15861-36-6) is a compound useful in organic synthesis.
Synthesis
4-Methyl-3-nitrobenzonitrile

939-79-7

Acetic acid

64-19-7

6-Cyanoindole

15861-36-6

To a stirred solution of 4-methyl-3-nitrobenzonitrile (16.58 g, 102.3 mmol) in 55 mL of N,N-dimethylformamide (DMF) was added N,N-dimethylacetamide (15.24 g, 128.1 mmol). The reaction mixture turned dark red and was subsequently stirred at 110 °C for 3 hours. After completion of the reaction, the solvent was removed under reduced pressure and the residue was dissolved in a mixture of 300 mL of ethanol and 300 mL of acetic acid. The reaction mixture was heated to 60 °C and iron powder (33 g, 594 mmol) was added in batches. The reaction mixture was refluxed for 2 h. After the reaction was completed, it was filtered through a Hyflo pad. Ether was added to the filtrate and the acidic layer was extracted with ether (1×). The ether layers were combined and concentrated in vacuum. The residue was purified by silica gel column chromatography using dichloromethane as eluent to give 7.02 g (48% yield) of 6-cyanoindaha solid.

References[1] Patent: US2006/122189, 2006, A1. Location in patent: Page/Page column 20
6-Cyanoindole Preparation Products And Raw materials
Raw materials4-Methyl-3-nitrobenzonitrile-->Acetic acid-->Iron-->N,N-Dimethylformamide-->Ethanol
Preparation Products6-Cyanogramine-->3-FORMYL-1H-INDOLE-6-CARBONITRILE-->6-Cyano-2-(4-cyanophenyl)indole
Tag:6-Cyanoindole(15861-36-6) Related Product Information
Methylene dithiocyanate Indole-3-butyric acid Indole 2-Methylindole Indole-3-acetic acid Indometacin Indole-6-carboxylic acid 6-Hydroxyindole 3-HYDROXY-1-PHENYL-6-PYRIDAZONE 6-cyanopyridine-3-boronic acid 6-CHLOROINDOLE-3-ACETONITRILE 6-chloropyrazine-2-carbonitrile 6-CHLORO-2,3-DIHYDRO-1H-INDOLE 6-Cyanopyridine-2-carboxylic acid 6-Chloroindole 2,3-DIHYDRO-1H-INDOLE-6-CARBONITRILE HYDROCHLORIDE 6-Hydroxyindolin-2-one Indole-3-carboxaldehyde