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| | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS Basic information | | Reactions |
| Product Name: | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS | | Synonyms: | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS;97% t-Bu-XANTPHOS;9,9-DiMethyl-4,5-bis(di-t-butylphosphino)xanthene,97% t-Bu-XANTPHOS;4,5-Bis[di(tert-butyl)phosphino]-9,9-dimethyl-9H-xanthene;9,9-DiMethyl-4,5-bis(di-t-butylphosphino)xanthene, 99% t-Bu-XANTPHOS;9,9-Dimethyl-4,5-bis(di-tert-butylphosphino)xanthene 97%;(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(di-tert-butylphosphine);9,9-Dimethyl-4,5-bis(di-t-butylphosphino)xanthene, min. 97% | | CAS: | 856405-77-1 | | MF: | C31H48OP2 | | MW: | 498.67 | | EINECS: | | | Product Categories: | organophosphine ligand;Indoles ,Indazoles;Achiral Phosphine;Aryl Phosphine | | Mol File: | 856405-77-1.mol |  |
| | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS Chemical Properties |
| Melting point | 153-157℃ | | Boiling point | 563.1±50.0 °C(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | color | white to light yellow | | InChI | 1S/C31H48OP2/c1-27(2,3)33(28(4,5)6)23-19-15-17-21-25(23)32-26-22(31(21,13)14)18-16-20-24(26)34(29(7,8)9)30(10,11)12/h15-20H,1-14H3 | | InChIKey | ZEIZANJFJXHMNS-UHFFFAOYSA-N | | SMILES | CC(C)(C)P(c1cccc2c1Oc3c(cccc3C2(C)C)P(C(C)(C)C)C(C)(C)C)C(C)(C)C | | CAS DataBase Reference | 856405-77-1 |
| Risk Statements | 36/37/38 | | Safety Statements | 26-37 | | WGK Germany | 3 | | TSCA | No | | Storage Class | 11 - Combustible Solids |
| | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS Usage And Synthesis |
| Reactions |
- Ligand used in the cobalt-catalyzed alkenylzincation of unfunctionalized alkynes.
- Ligand used in the cobalt-catalyzed alkylboration of alkenes.
- Ligand used in the palladium-catalyzed N-alkylation of amines using primary and secondary alcohols.
- Ligand used in the palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reagent type: ligand |
| | 9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS Preparation Products And Raw materials |
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