BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE manufacturers
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| | BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE Basic information |
| | BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE Chemical Properties |
| Melting point | 106-125 °C | | storage temp. | 2-8°C, sealed storage, away from moisture | | solubility | sol MeCN, MeNO3, DMSO, DMF; slightly sol MeOH, EtOH, AcOH, AcOEt, CHCl3, CH2Cl2; insol C6H14, CCl4, C6H6, H2O. | | form | powder to crystal | | color | Light yellow to Brown | | BRN | 4619219 | | InChI | 1S/C10H16N.Cl4I/c1-11(2,3)9-10-7-5-4-6-8-10;1-5(2,3)4/h4-8H,9H2,1-3H3;/q+1;-1 | | InChIKey | IBXYFQYYVRYALP-UHFFFAOYSA-N | | SMILES | Cl[I-](Cl)(Cl)Cl.C[N+](C)(C)Cc1ccccc1 | | CAS DataBase Reference | 121309-88-4 |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 1759 8/PG 2 | | WGK Germany | 3 | | F | 4.4-8 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29239000 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Skin Corr. 1B |
| | BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE Usage And Synthesis |
| Uses | Benzyltrimethylammonium tetrachloroiodate is a chlorinating agent for aromatic compounds; it can be used for side chain chlorination of aromatic compounds and chlorine addition of olefins. | | Preparation | Chlorine gas was passed into a solution of benzyltrimethylammonium chloride (18.6 g, 0.1 mol) and iodine (12.7 g, 0.05 mol) in CH2Cl2 (300 mL) for 15 min; the yield of BEnzyltrimethylammonium tetrachloroiodate was 40 g (95%). | | storage | Stable solid, but gradually decomposes with evolution of Cl2 when in contact with air for a long time. This reagent should be handled in a fume hood. |
| | BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE Preparation Products And Raw materials |
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