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Diphenyldimethoxysilane

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Diphenyldimethoxysilane Basic information
Product Name:Diphenyldimethoxysilane
Synonyms:dimethoxydiphenyl-silan;Diphenyldimethoxylsilane;diphenyldimethoxylsilicane;kbm202;kbm202ls5300;tsl8172;z6074;Benzene,1,1'-(diMethoxysilylene)bis-
CAS:6843-66-9
MF:C14H16O2Si
MW:244.36
EINECS:229-929-1
Product Categories:Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Organosilicon;Others;Self Assembly &;Self-Assembly Materials;Silanes;organosilicon compounds;Dialkoxysilanes;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Phenyl Silanes;silane
Mol File:6843-66-9.mol
Diphenyldimethoxysilane Structure
Diphenyldimethoxysilane Chemical Properties
Melting point <0°C
Boiling point 161 °C15 mm Hg(lit.)
density 1.08 g/mL at 20 °C(lit.)
vapor pressure 0.03Pa at 25℃
refractive index n20/D 1.541
Fp 121°C
storage temp. Inert atmosphere,Room Temperature
form liquid
color colorless
Specific Gravity1.0771
Water Solubility 3mg/L at 20℃
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 2940458
InChI1S/C14H16O2Si/c1-15-17(16-2,13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,1-2H3
InChIKeyAHUXYBVKTIBBJW-UHFFFAOYSA-N
SMILESCO[Si](OC)(c1ccccc1)c2ccccc2
CAS DataBase Reference6843-66-9(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, dimethoxydiphenyl-(6843-66-9)
EPA Substance Registry SystemSilane, dimethoxydiphenyl- (6843-66-9)
Safety Information
Hazard Codes Xi
Risk Statements 38
Safety Statements 28-37-24/25
WGK Germany 2
RTECS VV3643332
10-21
TSCA TSCA listed
HS Code 29319090
Storage Class10 - Combustible liquids
Hazard ClassificationsSkin Irrit. 2
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diphenyldimethoxysilane Usage And Synthesis
Chemical PropertiesColorless clear liquid
UsesReagent for preparation of diphenylsilylene derivatives of diols by exchange.
UsesDMDPS may be useful as a precursor to prepare silica.{58} It?may be used in lithium ion batteries as an electrolyte additive. It prevents the batteries from overcharging.{59}
General DescriptionDimethoxydiphenylsilane (DMDPS, DDS) is an acetylating reagent.{57}
Flammability and ExplosibilityNon flammable
Synthesis
Methanol

67-56-1

Diphenylsilane

775-12-2

Diphenyldimethoxysilane

6843-66-9

General procedure: the synthesis was carried out using a standard catalytic CDC reaction scheme. In an inert atmosphere glove box, the precatalyst (0.05 mmol) was accurately weighed and added to a Schlenk tube, followed by the sequential addition of methanol (n × 0.05 mmol, n-equivalent) and diphenylsilane (n' × 0.05 mmol, n' equivalent). The reaction mixture was placed in a 30°C oil bath with constant temperature stirring for the reaction. Upon completion of the reaction, the reaction was quenched by the addition of CDCl3. The reaction mixture was analyzed using 1H NMR spectroscopy and the reaction conversion was monitored by comparing the relative intensities of the characteristic peaks of the substrate and the product.

References[1] Australian Journal of Chemistry, 2017, vol. 70, # 6, p. 724 - 730
[2] Chemische Berichte, 1995, vol. 128, # 12, p. 1267 - 1270
[3] Journal of Organometallic Chemistry, 2004, vol. 689, # 20, p. 3258 - 3264
[4] ACS Catalysis, 2018, vol. 8, # 3, p. 2558 - 2566
[5] Chemistry Letters, 1973, p. 501 - 504
Diphenyldimethoxysilane Preparation Products And Raw materials
Raw materialsMethanol-->Dichlorodiphenylsilane-->Tetramethyl orthosilicate-->Bromobenzene-->Trimethoxyphenylsilane-->Diphenylsilane-->Manganese, diphenyl--->PHENYLMAGNESIUM CHLORIDE
Preparation Products4-Methylbenzhydrol
Tag:Diphenyldimethoxysilane(6843-66-9) Related Product Information
Diphenyldiethoxysilane Dimethoxymethylphenylsilane Methylphenyldiethoxysilane Trimethoxyphenylsilane Methyldimethoxysilane Triethoxysilane Diethoxymethylsilane Dimethoxydicyclopentylsilane Trimethoxysilane Diphenylsilanediol Methyltriethoxysilane Dichlorodiphenylsilane Dimethyldimethoxysilane Triethoxyvinylsilane Diphenylsilane 1,1-Dimethoxyethane Ethyl silicate Dimethoxymethane

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