(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane

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(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane manufacturers

(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane Basic information
Product Name:(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane
Synonyms:(R)-Phanephos, 98%, ee 98%;(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%;(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee;(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane;12,43-bis(diphenylphosphaneyl)-1,4(1,4)-dibenzenacyclohexaphane
CAS:364732-88-7
MF:C40H34P2
MW:576.65
EINECS:
Product Categories:Chiral Phosphine;PHANEPhos Series
Mol File:364732-88-7.mol
(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane Structure
(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane Chemical Properties
Melting point 222-225°C
alpha -62.6° (c 3.11, CH2Cl2)
storage temp. Inert atmosphere,Room Temperature
form solid
color white
Optical Rotation[α]/D -34±4°, c = 1 in chloroform
InChIKeyGYZZZILPVUYAFJ-UHFFFAOYSA-N
SMILESP(c7ccccc7)(c6ccccc6)c1c2ccc(c1)CCc3c(cc(cc3)CC2)P(c5ccccc5)c4ccccc4
CAS DataBase Reference364732-88-7
Safety Information
Hazard Codes Xi
Risk Statements 37
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane Usage And Synthesis
UsesEfficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.
(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane Preparation Products And Raw materials
Tag:(R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane(364732-88-7) Related Product Information
Diphenylphosphine (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane (S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane ,CTH-(S)-3,5-xylyl-phanephos (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane (R)-An-Phanephos