2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole

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CAS:672937-60-9
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CAS:672937-60-9
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2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole Basic information
Reactions
Product Name:2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole
Synonyms:2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole;cataCXium(R) PCy;2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole 95%;N-Phenyl-2-(dicyclohexylphosphino)pyrrole [cataCXiuM PCy];Dicyclohexyl(1-phenyl-1H-pyrrol-2-yl)phosphine;N-Phenylpyrrol-2-yldicyclohexylphosphine;N-Phenyl-2-(dicyclohexylphosphino)pyrrole,90%;N-Phenyl-2-(dicyclohexylphosphino)pyrrole, 90% [cataCXium(R) PCy]
CAS:672937-60-9
MF:C22H30NP
MW:339.45
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine
Mol File:672937-60-9.mol
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole Structure
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole Chemical Properties
Melting point 92°C
Boiling point 482.8±18.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
pka-6.24±0.70(Predicted)
color white to yellow
Sensitive air sensitive
BRN 9649724
InChI1S/C22H30NP/c1-4-11-19(12-5-1)23-18-10-17-22(23)24(20-13-6-2-7-14-20)21-15-8-3-9-16-21/h1,4-5,10-12,17-18,20-21H,2-3,6-9,13-16H2
InChIKeyRVFZOTGUPNHVRA-UHFFFAOYSA-N
SMILESC1CCC(CC1)P(C2CCCCC2)c3cccn3-c4ccccc4
CAS DataBase Reference672937-60-9
Safety Information
WGK Germany 3
HS Code 29339900
Storage Class11 - Combustible Solids
MSDS Information
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole Usage And Synthesis
Reactions
  1. Useful ligand for the Ru-catalyzed amination of diols.
  2. Direct amination of secondary alcohols with ammonia.
  3. Amino-alcohol cyclization to lactams or cyclic amines. 
Reactions of 672937-60-9
Chemical PropertiesWhite to yellow powder
General Descriptionsold in collaboration with Solvias AG
reaction suitabilityreaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Aminations
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole Preparation Products And Raw materials
Tag:2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole(672937-60-9) Related Product Information
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole 1-(2-METHOXYPHENYL)-2-(DICYCLOHEXYLPHOSPHINO)PYRROLE 2-(Dicyclohexylphosphino)-1-phenylindole