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| | BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE Basic information |
| | BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE Chemical Properties |
| Melting point | 166-170 °C(lit.) | | storage temp. | Inert atmosphere,2-8°C | | solubility | sol THF, benzene, and other organic solvents | | form | Crystalline Powder | | color | Yellow | | InChI | 1S/2C18H15P.C7H7.ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-6H,1H2;1H;/q;;;;+1/p-1 | | InChIKey | PVJAZFSARQVMGK-UHFFFAOYSA-M | | SMILES | Cl[Pd]Cc1ccccc1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7 |
| Hazard Codes | Xn | | Risk Statements | 20/21/22-36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | HS Code | 28439000 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| | BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE Usage And Synthesis |
| Chemical Properties | Yellow crystalline powder | | Uses | Catalyst for the cross coupling1 of alkyl-, vinyl-, alkynyl-, and allylstannane groups with acyl chlorides, allyl halides, vinyl triflates, and iodides. | | reaction suitability | core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst | | Synthesis | The preparative method of Benzylbis(triphenylphosphine)palladium(II) chloride: may be prepared from benzyl chloride and (Ph3P)4Pd in benzene at room temperature, washed with Et2O, and dried under vacuum.
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| | BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE Preparation Products And Raw materials |
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