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2,2,2-Trifluoroethyl methacrylate

2,2,2-Trifluoroethyl methacrylate Suppliers list
Company Name: AS WATER CO., LTD.
Tel: +86-18994963526 +8618994963526
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Products Intro: Product Name:2,2,2-Trifluoroethyl Methacrylate
CAS:352-87-4
Purity:0.95 Package:25KG;180KG Remarks:Material intermediates
Company Name: Hebei Chuanghai Biotechnology Co., Ltd
Tel: +8615350571055
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Products Intro: Product Name:2,2,2-Trifluoroethyl methacrylate
CAS:352-87-4
Purity:99% Package:1KG;10.00;USD
Company Name: Hebei Chuanghai Biotechnology Co,.LTD
Tel: +86-86-13131129325 +8613131129325
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Products Intro: Product Name:trifluoroethyl methacrylate
CAS:352-87-4
Purity:99% Package:1KG;9.00;USD|1KG;9.00;USD
Company Name: Henan Bao Enluo International TradeCo.,LTD
Tel: +86-17331933971
Email: deasea125996@gmail.com
Products Intro: Product Name:2,2,2-Trifluoroethyl methacrylate
CAS:352-87-4
Purity:99.99% Package:1kg;20USD
Company Name: Hebei Zhuanglai Chemical Trading Co Ltd
Tel: +86-16264648883
Email: niki@zlchemi.com
Products Intro: Product Name:2,2,2-Trifluoroethyl methacrylate
CAS:352-87-4
Purity:99% Package:1kg;60USD

2,2,2-Trifluoroethyl methacrylate manufacturers

  • 2,2,2-Trifluoroethyl methacrylate
  • 2,2,2-Trifluoroethyl methacrylate pictures
  • $50.00 / 100kg
  • 2025-10-13
  • CAS:352-87-4
  • Min. Order: 1kg
  • Purity: 99%,Electronic grade(Single metal impurity≤ 100ppb)
  • Supply Ability: 100kg
2,2,2-Trifluoroethyl methacrylate Basic information
Uses Uses
Product Name:2,2,2-Trifluoroethyl methacrylate
Synonyms:TRIFLUOROETHANOLMETHACRYLATE;2,2,2-Trifluorethylmethacrylat;2,2,2-Trifluoroethyl 2-methyl-2-propenoate;Acryester 3FE;Fluorester;Light Ester M 3F;2,2,2-Trifluoroethyl methacrylate, 98%, stab. with 30-50ppm 4-methoxyphenol;2,2,2-Trifluoroethyl Methacrylate (stabilized with MEHQ)
CAS:352-87-4
MF:C6H7F3O2
MW:168.11
EINECS:206-525-3
Product Categories:Acrylic Monomers;C6 to C7Monomers;Carbonyl Compounds;Esters;Fluorinated AcrylicsPhotonic and Optical Materials;Low Refractive Index Monomers;Waveguide Materials;monomer;Halogenated Heterocycles;352-87-4
Mol File:352-87-4.mol
2,2,2-Trifluoroethyl methacrylate Structure
2,2,2-Trifluoroethyl methacrylate Chemical Properties
Boiling point 59 °C100 mm Hg(lit.)
density 1.181 g/mL at 25 °C(lit.)
vapor pressure 22hPa at 20℃
refractive index n20/D 1.361(lit.)
Fp 62 °F
storage temp. 2-8°C
form Crystals or Crystalline Powder
Specific Gravity1.181
color White
Water Solubility 906mg/L at 20℃
BRN 4175872
Cosmetics Ingredients FunctionsFILM FORMING
InChI1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChIKeyQTKPMCIBUROOGY-UHFFFAOYSA-N
SMILESCC(=C)C(=O)OCC(F)(F)F
LogP2.3 at 23.3℃
CAS DataBase Reference352-87-4(CAS DataBase Reference)
NIST Chemistry Reference2,2,2-Trifluoroethyl methacrylate(352-87-4)
EPA Substance Registry System2,2,2-Trifluoroethyl methacrylate (352-87-4)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-37/39
RIDADR UN 3272 3/PG 2
WGK Germany 2
Hazard Note Flammable/Keep Cold
TSCA TSCA listed
HazardClass 3
PackingGroup II
HS Code 29161400
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Chronic 3
Flam. Liq. 2
MSDS Information
ProviderLanguage
2,2,2-Trifluoroethyl methacrylate English
SigmaAldrich English
ACROS English
ALFA English
2,2,2-Trifluoroethyl methacrylate Usage And Synthesis
Uses2,2,2-TRIFLUOROETHYL METHACRYLATE is a useful research chemical.
Uses2,2,2-Trifluoroethyl methacrylate is mainly used for coating to improve its weather resistance, water resistance and pollution resistance. It can also be used as a charge regulator for cladding and core materials of optical fibers, contact lenses, toner and carrier particles of computers.
Chemical Propertiesclear colorless liquid
UsesTFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.
General Description2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant.
Flammability and ExplosibilityHighly flammable
Synthesis

The present invention discloses a method for the preparation of trifluoroethyl methacrylate. Trifluoroethanol and methacryloyl chloride are used as raw materials, and the esterification reaction is carried out under the protection of a polymerization blocking agent, and then the target product trifluoroethyl methacrylate is collected from the reaction product. The purity of trifluoroethyl methacrylate obtained by the method of the present invention is more than 99%, the yield is more than 80%, and the boiling point is 100.8-101.2°C. Compared with the prior art, the present invention has mild reaction conditions.

2,2,2-Trifluoroethyl methacrylate Preparation Products And Raw materials
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