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| | Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Basic information | | Reaction |
| Product Name: | Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO | | Synonyms: | Ru-MACHO(regR);Ru-MACHO(regR) (contains 5% Toluene at maximum);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO;Ru-MACHO (contains 5% Toluene at maximum)
;Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM);Ru-MACHO[R] (contains 5% Toluene at maximum);Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II) | | CAS: | 1295649-40-9 | | MF: | C29H31ClNOP2Ru | | MW: | 608.04 | | EINECS: | | | Product Categories: | | | Mol File: | 1295649-40-9.mol | ![Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Structure](CAS/20211123/GIF/1295649-40-9.gif) |
| | Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Chemical Properties |
| Melting point | 260-290 °C | | storage temp. | 2-8°C, stored under nitrogen | | form | Powder | | color | white to yellow | | Sensitive | air sensitive | | InChI | 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1 | | InChIKey | GQFWSAKCCNATEV-UHFFFAOYSA-M | | SMILES | Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4 | | CAS DataBase Reference | 1295649-40-9 |
| WGK Germany | WGK 3 | | HS Code | 2843.90.0000 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Usage And Synthesis |
| Reaction |
- Highly efficient ruthenium-catalyzed used in the N-formylation of amines with hydrogen and carbon dioxide.
- Rutheniumcatalyzed hydrogen generation from glycerol and selective synthesis of lactic acid
| | Uses | <ul>
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul> | | reaction suitability | core: ruthenium
reagent type: catalyst |
| | Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Preparation Products And Raw materials |
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