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Tralkoxydim

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CAS:87820-88-0
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CAS:87820-88-0
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CAS:87820-88-0
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CAS:87820-88-0
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Company Name: TargetMol Chemicals Inc.
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Products Intro: Product Name:Tralkoxydim
CAS:87820-88-0
Purity:98.22% Package:5mg;50USD|10mg;70USD|25mg;114USD Remarks:REAGENT;FOR LABORATORY USE ONLY

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Tralkoxydim Basic information
Physical and Chemical Properties InChI Code Toxicity Application Synthesis
Product Name:Tralkoxydim
Synonyms:2-[1-(ethoxyimino) propyl]-3-hydroxy-5-mestiylcyclohexen-2-one;Fd 4026;Hsdb 7016;Ici-A 604;Tralkoxydim 500mg [87820-88-0];GRASP;Achiveve;Grasp 604
CAS:87820-88-0
MF:C20H27NO3
MW:329.43
EINECS:252-615-0
Product Categories:Cyclohexene oximePesticides&Metabolites;TP - TZ;Alpha sort;Herbicides;Pesticides&Metabolites;Q-ZAlphabetic
Mol File:87820-88-0.mol
Tralkoxydim Structure
Tralkoxydim Chemical Properties
Melting point 106°
Boiling point 467.02°C (rough estimate)
density 1.1213 (rough estimate)
refractive index 1.5614 (estimate)
Fp >100 °C
storage temp. 0-6°C
solubility soluble in dichloromethane,Toluene,Acetone
pka4.20±0.25(Predicted)
color Light yellow to Yellow to Orange
Merck 14,9564
BRN 8577523
Henry's Law Constant4.1×104 mol/(m3Pa) at 25℃, HSDB (2015)
InChIInChI=1S/C20H27NO3/c1-6-16(21-24-7-2)20-17(22)10-15(11-18(20)23)19-13(4)8-12(3)9-14(19)5/h8-9,15,22H,6-7,10-11H2,1-5H3
InChIKeyDQFPEYARZIQXRM-UHFFFAOYSA-N
SMILESC1(=O)CC(C2=C(C)C=C(C)C=C2C)CC(O)=C1C(=NOCC)CC
LogP4.460
CAS DataBase Reference87820-88-0(CAS DataBase Reference)
EPA Substance Registry SystemTralkoxydim (87820-88-0)
Safety Information
Hazard Codes Xn
Risk Statements 22
RIDADR UN 3077 9 / PGIII
WGK Germany 3
RTECS GW7191600
HazardClass 9
PackingGroup III
HS Code 29280000
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Aquatic Chronic 2
Carc. 2
Hazardous Substances Data87820-88-0(Hazardous Substances Data)
ToxicityLD50 orally in male and female rats, male and female mice, male rabbit (mg/kg): 1324, 934, 1231, 1100, 519; dermally in male and female rats: >2000, >2000 mg/kg (Warner 1987)
Tralkoxydim Usage And Synthesis
Physical and Chemical PropertiesAppearance: White tasteless crystalline solid
Melting Point: 106℃
Saturated Vapor Pressure: 4×10-7Pa (<0.013×10-3Pa 20℃)
Solubility: 4×10-7Pa (<0.013×10-3Pa 20℃) in dichloromethane at 24℃, 213g/L in methylbenzene at 24℃, 110g/L in ethyl acetate at 24℃, 89g/L in acetone at 24℃, 25g/L in methanol at 24℃, 18g/L in hexane at 24℃.
6mg/L (pH=6.5) and 5mg/L (pH=5.0) in water at 20℃
InChI Code1S/C20H27NO3/c1-6-16(21-24-7-2)20-17(22)10-15(11-18(20)23)19-13(4)8-12(3)9-14(19)5/h8-9,15,22H,6-7,10-11H2,1-5H3
ToxicityP.O. acute toxicity: LD50=1324mg/kg for male rats, LD50=934mg/kg for female rats,  LD50=1321mg/kg for male mice, LD50=1100mg/kg for female mice, LD50>519mg/kg for rabbits.
Non-effect dose for rats in three-month feed test is 12.5mg/kg. LD50=3020mg/kg for mallard, LD50=4430mg/kg for partridge.
Acute percutaneous toxicity: LD50>2000mg/kg for male and female rats.
Acute inhalation toxicity: LC50>3467mg/m3 for male and female rats.
It has mild irritation on eyes and skin. No allergic effect on cavy.
No teratogenesis effect has been observed yet.
LC50>7.2mg/L (96h) for rainbow trout, LC50>8.2mg/L (96h) for Cyprinus carpio var.
ApplicationTralkoxydim is a kind of highly selective herbicide with inward absorption and conduction ability. It’s used on a variety of graminaceous weeds in barley and wheat fields. It is rapidly absorbed and transferred throughout all parts of the weeds after foliar spray. The weeds will soon turn pale and wither. The general dosage is 150~350g effective constituent/hm2 . 200~350g effective constituent /hm2 of tralkoxydim applied from early growth period to elongation stage will be effective on the prevention and control of wild oat weeds.
SynthesisThe product of the reaction between 2,4,6-Trimethylbenzaldehyde and acetone react with diethyl malonate to generate an intermediate. The intermediate is transformed into 3-hydroxy-5-(2',4',6'-trimethylphenyl)-cyclohexyl-2-alkenyl-1-ketone after hydrolysis, cyclization and decarboxylation. Then it reacts with propionic anhydride in the presence of sodium methanol. The product reacts with ethoxyamine hydrochloride to generate methoxyphenone.
UsesPost-emergent herbicide.
DefinitionChEBI: Tralkoxydim is a mixture.
Agricultural UsesHerbicide: Tralkoxydim is a post-emergent herbicide applied to actively growing weeds in wheat, barley, triticale and cereal rye to control wild oats, green foxtail, yellow foxtail, annual ryegrass and Persian darnel. Registered for use in EU countries. Registered for use in the U.S.
Trade nameACHIEVE®; ACHIEVE®-40DG; ALPHA GRASP®; ICI-A 604®; PP 604®; SPLENDOR®
Tralkoxydim Preparation Products And Raw materials
Raw materialsPropionic anhydride-->Ethoxyamine hydrochloride-->2-Cyclohexen-1-one-->Mesitaldehyde-->METHOXYPHENONE
Tag:Tralkoxydim(87820-88-0) Related Product Information
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