|
|
| | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Basic information |
| | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Chemical Properties |
| Melting point | 180-182℃ | | Boiling point | 185°C 0,01mm | | density | 1,15 g/cm3 | | refractive index | 1.5030 | | Fp | 185°C/0.01mm | | storage temp. | Inert atmosphere,2-8°C | | solubility | sol THF, DMF | | form | liquid | | Specific Gravity | 1.150 | | color | Orange | | Water Solubility | Miscible with terahydrofuran and dimethyl formamide. Slightly miscible with water. | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | Sensitive | Air & Moisture Sensitive | | BRN | 3613803 | | InChIKey | VNKOWRBFAJTPLS-UHFFFAOYSA-N |
| Provider | Language |
|
ALFA
| English |
| | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Usage And Synthesis |
| Chemical Properties | colorless to slightly yellow liquid | | Uses | trans-1,2-Bis(tri-n-butylstannyl)ethylene can be used in versatile vinyl anion synthon: efficiently monotransmetalated by alkyllithium reagents and higher order organocuprates; palladium-catalyzed coupling with a variety of electrophilic partners affords substituted vinylstannanes. | | Preparation | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE is prepared in high yield by the reductive hydrostannation of tributylstannylacetylene with Tri-n-butylstannane and catalytic Azobisisobutyronitrile. | | Preparation | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE can be purified by distillation or by preparative reverse-phase chromatography. |
| | TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE Preparation Products And Raw materials |
|