4,5-Dibromo-3-methylthiophene-2-carboxylic acid

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4,5-Dibromo-3-methylthiophene-2-carboxylic acid Basic information
Product Name:4,5-Dibromo-3-methylthiophene-2-carboxylic acid
Synonyms:4,5-dibromo-3-methyl-2-Thiophenecarboxylic acid;4,5-Dibromo-3-methylthiophene-2-carboxylic acid;2-Thiophenecarboxylic acid, 4,5-dibromo-3-methyl-
CAS:854626-32-7
MF:C6H4Br2O2S
MW:299.97
EINECS:
Product Categories:
Mol File:854626-32-7.mol
4,5-Dibromo-3-methylthiophene-2-carboxylic acid Structure
4,5-Dibromo-3-methylthiophene-2-carboxylic acid Chemical Properties
Melting point 225-226 °C
Boiling point 369.8±42.0 °C(Predicted)
density 2.141±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka3.48±0.10(Predicted)
AppearanceWhite to off-white Solid
Safety Information
MSDS Information
4,5-Dibromo-3-methylthiophene-2-carboxylic acid Usage And Synthesis
Preparation4,5-Dibromo-3-methyl-2-thiophenecarboxylic acid synthesis: 4,5-dibromo-3-methyl-2-thiophenecarbonitrile (26.2 g, 92.2 mmol), EtOH (175 mL), water (175 mL), and NaOH (18.6 g, 466 mmol) were stirred together at 80°C for 1 h. The solvent was removed, the solids were collected by filtration, dissolved in water, and washed with CH2Cl2. The water layer was acidified with 37% HCl, the white solid was collected by filtration and dried under vacuum at 60°C to give 25.9 g (94% wt.) of 4,5-dibromo-3-methyl-2-thiophenecarboxylic acid: m.p. 225-226°C; 1H NMR (CDCl3) 2.5 (s).
4,5-Dibromo-3-methylthiophene-2-carboxylic acid Preparation Products And Raw materials
Raw materialsEthyl acetate
Tag:4,5-Dibromo-3-methylthiophene-2-carboxylic acid(854626-32-7) Related Product Information
4-Bromo-3-methylthiophenecarboxylic acid 5-Bromo-3-methylthiophene-2-carboxylic acid 4,5-Dibromothiophene-2-carboxylic acid 4,5-Dibromo-3-methyl-thiophene-2-carboxylic acid methyl ester 4,5-Dibromo-3-methylthiophene-2-carbaldehyde 4,5-Dibromo-3-methylthiophene-2-carbonitrile