1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE manufacturers
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| | 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE Basic information |
| Product Name: | 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE | | Synonyms: | N-Fluoro-2,4,6-trimethylpyridinium triflate,85-90%;Florinate FP-T 300;FP-T 300;Onoda Florinate FP-T 300;N-Fluoro-2,4,6-trimethylpyridinium triflate, N-Fluoro-2,4,6-collidinium triflate;N-Fluoro-2,4,6-trimethylpyridinium trifluoromethanesulphonate 97%;N-Fluoro-2,4,6-trimethylpyridiniumtrifluoromethanesulphonate97%;N-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE | | CAS: | 107264-00-6 | | MF: | C9H11F4NO3S | | MW: | 289.25 | | EINECS: | | | Product Categories: | Pyridinium Compounds;Synthetic Organic Chemistry;Electrophilic Fluorinating Reagents;Fluorinating Reagents;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Fluorination;Halogenation | | Mol File: | 107264-00-6.mol |  |
| | 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE Chemical Properties |
| Melting point | 162-165 °C(lit.) | | density | 1.3855 (estimate) | | storage temp. | 2-8°C | | form | Powder | | color | white to pale-yellow | | Sensitive | air sensitive, moisture sensitive, store cold | | BRN | 4777118 | | InChI | InChI=1S/C8H11FN.CHF3O3S/c1-6-4-7(2)10(9)8(3)5-6;2-1(3,4)8(5,6)7/h4-5H,1-3H3;(H,5,6,7)/q+1;/p-1 | | InChIKey | PRIGFEJKMMRJSF-UHFFFAOYSA-M | | SMILES | C(F)(F)(F)S([O-])(=O)=O.[N+]1(F)C(C)=CC(C)=CC=1C | | CAS DataBase Reference | 107264-00-6(CAS DataBase Reference) |
| Hazard Codes | Xi,C | | Risk Statements | 34 | | Safety Statements | 26-27-28-36/37/39-45-36 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | No | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29333990 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Skin Corr. 1B |
| | 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE Usage And Synthesis |
| Chemical Properties | white crystalline powder | | Uses | N-fluoropyridinium triflate salts offer a tunable fluorinating system; electronic nature of the substituents on the ring dictates the potency and selectivity of the reagent. Efficient fluorination of various aromatics, carbanions, vinyl esters, alkyls, and enamines. | | Uses | Reactant for:
- Pd(II)-catalyzed para-selective C-H arylation
- Fluorination reactions
- Oxidant in oxidatively-induced aryl-CF3 bond-formation
- Pd(II)-catalyzed C-H olefination reactions
| | reaction suitability | reagent type: catalyst
reaction type: Fluorinations
reagent type: oxidant
reaction type: C-H Activation |
| | 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE Preparation Products And Raw materials |
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