1-Methyl-3-piperidinemethanol

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1-Methyl-3-piperidinemethanol manufacturers

1-Methyl-3-piperidinemethanol Basic information
Synthesis
Product Name:1-Methyl-3-piperidinemethanol
Synonyms:(1-methyl-3-piperidyl)methanol;N-Methylpiperidine-3-methanol;1-Methyl-3-piperidinemethanol,97%;3-HYDROXYMETHYL-1-METHYLPIPERIDINE;3-HYDROXYMETHYL-N-METHYLPIPERIDINE;1-METHYL-3-PIPERIDINEMETHANOL;1-METHYLPIPERIDINE-3-METHANOL;N-METHYL-3-PIPERIDINE METHANOL
CAS:7583-53-1
MF:C7H15NO
MW:129.2
EINECS:231-488-5
Product Categories:Piperidine;Heterocyclic Compounds
Mol File:7583-53-1.mol
1-Methyl-3-piperidinemethanol Structure
1-Methyl-3-piperidinemethanol Chemical Properties
Boiling point 140-145 °C
density 1.01
refractive index 1.4772-1.4792
Fp 94 °C
storage temp. Sealed in dry,Room Temperature
pka14.93±0.10(Predicted)
form clear liquid
color Colorless to Yellow to Orange
BRN 103713
CAS DataBase Reference7583-53-1(CAS DataBase Reference)
NIST Chemistry Reference1-Methyl-3-piperidinemethanol(7583-53-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-45-36/37/38-23
HazardClass IRRITANT
PackingGroup III
HS Code 29333990
MSDS Information
ProviderLanguage
1-Methyl-3-piperidinemethanol English
ACROS English
ALFA English
1-Methyl-3-piperidinemethanol Usage And Synthesis
SynthesisUnder argon protection, appropriate amounts of lithium aluminum hydride (2 mol) and dry tetrahydrofuran were added to a dry reaction flask. The reaction system was then cooled to zero degrees Celsius, followed by the addition of the precursor compound ester (1 mol). After the addition was complete, the reaction system was heated to 40-50 degrees Celsius and stirred for 2 hours, then stirred overnight at room temperature. After the reaction was complete, the reaction was quenched by adding H₂O, and a cooling NaOH aqueous solution was added as needed. The solution was then filtered, the solid was washed with dry tetrahydrofuran, the filtrate was dried with anhydrous sodium sulfate, and the sodium sulfate solid was removed by filtration. The filtrate was concentrated under vacuum to obtain the target product, 1-Methyl-3-piperidinemethanol.
Chemical Propertiesclear colorless to yellow liquid
UsesHydroxymethyl-N-methylpiperidine is used in the preparation of pyrimidines as FGFR3 tyrosine kinase inhibitors as well as for potent pyrazine c-Src inhibitors in the treatment of ischemic stroke.
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