Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V)

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Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V) Basic information
Product Name:Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V)
Synonyms:Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium;(OC-6-21)-Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium;Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V)
CAS:108695-90-5
MF:C20H22Cl3O2PReS
MW:649.98
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhenium
Mol File:108695-90-5.mol
Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V) Structure
Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V) Chemical Properties
form powder
InChI1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChIKeyGIBDGLAUIKUJJX-UHFFFAOYSA-K
SMILESCSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V) Usage And Synthesis
UsesCatalyst for:
  • Enantioselective reduction of ketones and imines
  • Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
  • Synthesis of 2-deoxy-α glycosides
  • Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis
reaction suitabilitycore: rhenium
reagent type: catalyst
Oxotrichloro(dimethylsulfide)triphenylphosphine oxide)rhenium(V) Preparation Products And Raw materials
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