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S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate

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Products Intro: Product Name:S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS:129946-88-9
Purity:97%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
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Products Intro: Product Name:129946-88-9 S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS:129946-88-9
Purity:99% Package:25KG;5KG;1KG
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Products Intro: Product Name:5-(Trifluoromethyl)dibenzothiophenium Trifluoromethanesulfonate
CAS:129946-88-9
Purity:>95% Package:0.25g;1g;5g;10g;25g;100g
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Products Intro: Product Name:5-(Trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate
CAS:129946-88-9
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-24814
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Products Intro: Product Name:s-(trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS:129946-88-9
Purity:0.99 Package:1kg

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S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate Basic information
Product Name:S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
Synonyms:S-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TRIFLATE;S-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TRIFLUOROMETHANESULFONATE;S-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TRIFLUOROMETHANESULPHONATE;5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TRIFLUOROMETHANESULFONATE;5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TR;5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUMTETRAFLUOROMETHANESULFONATE;5-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate,96%;5-(Trifluoromethyl)dibenzo[b,d]thiophenium triflate, S-(Trifluoromethyl)dibenzo[b,d]thiophenium triflate
CAS:129946-88-9
MF:C14H8F6O3S2
MW:402.33
EINECS:
Product Categories:Benzothiophenes;Building Blocks;Heterocyclic Building Blocks;API intermediates
Mol File:129946-88-9.mol
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate Structure
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate Chemical Properties
Melting point 155 °C
density 7 g/cm3
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility DMSO (Slightly), Water (Slightly, Heated)
form Crystalline Powder
color White to tan
InChIInChI=1S/C13H8F3S.CHF3O3S/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)8(5,6)7/h1-8H;(H,5,6,7)/q+1;/p-1
InChIKeyQXXHXTRTGZBOGD-UHFFFAOYSA-M
SMILESC12C=CC=CC=1C1=C(C=CC=C1)[S+]2C(F)(F)F.C(F)(F)(F)S([O-])(=O)=O
CAS DataBase Reference129946-88-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-36
WGK Germany 3
Hazard Note Irritant
HS Code 29349990
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate Usage And Synthesis
Chemical PropertiesS-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate is white to pale brown crystalline powder
UsesS-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate. Electrophilic trifluoromethylation in ionic liquids. Used in the stereoselective preparation of trifluoromethylalkynes by trifluoromethylation of terminal alkynes using Umemoto′s reagent and a copper catalyst.
Uses5-(Trifluoromethyl)dibenzothiophenium 1,1,1-Trifluoromethanesulfonate is used in the synthesis of substituted isoxazolines. Also used in the synthesis of β-ketophosphonate derivatives as building blocks in automated syntheses.
storagenonhygroscopic and thermally stable crystals; should be stored in a dry atmosphere protected from light.
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate Preparation Products And Raw materials
Preparation Products1-Bromo-4-(2,2,2-trifluoroethyl)benzene-->2-(Trifluoromethyl)pyridine-->1-Nitro-4-(2,2,2-trifluoro-1-methyl-ethyl)benzene
Tag:S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate(129946-88-9) Related Product Information
2-(Trifluoromethyl)benzoic acid 4,6-DIMETHYLDIBENZOTHIOPHENE Phenylmethylsulfonyl fluoride 4-(Trifluoromethyl)benzaldehyde 4'-(Trifluoromethyl)acetophenone 3-(Trifluoromethyl)benzaldehyde Dibenzothiophene Benzotrifluoride S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate TRIMETHYLSULFONIUM HYDROXIDE 2-Phenylthiophenol S-(TRIFLUOROMETHYL)-3,7-DINITRODIBENZOTHIOPHENIUM TRIFLUOROMETHANESULFONATE 1-METHYL-2-TRIFLUOROMETHYLSULFANYL-BENZENE S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate