2-Diphenylphosphinobenzaldehyde

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2-Diphenylphosphinobenzaldehyde manufacturers

2-Diphenylphosphinobenzaldehyde Basic information

Product Name:	2-Diphenylphosphinobenzaldehyde
Synonyms:	Diphenylphosphinobenzaldehyde;(2-Formylphenyl)diphenylphosphine;o-(Diphenylphosphino)benzaldehyde;2-DiphenylphosphiNAbenzaldehyde;2- twophenylphosphinebenzaldehyde;2-(Diphenylphosphino)benzaldehyde, min. 97%;2-Diphenylphosphinobenzaldehyde（DPPBde）;2-(DIPHENYLPHOSPHINO)BENZALDEHYDE
CAS:	50777-76-9
MF:	C19H15OP
MW:	290.3
EINECS:
Product Categories:	Aldehydes;Building Blocks;C13-C60;Carbonyl Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Organic Building Blocks;Phosphine Ligands;Phosphorus Compounds;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds;phosphine ligand
Mol File:	50777-76-9.mol

2-Diphenylphosphinobenzaldehyde Chemical Properties

Melting point	112-115 °C(lit.)
Boiling point	417.4±28.0 °C(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Crystalline Powder
color	Yellow
λmax	376nm(CH2Cl2)(lit.)
InChI	InChI=1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H
InChIKey	DRCPJRZHAJMWOU-UHFFFAOYSA-N
SMILES	C(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference	50777-76-9(CAS DataBase Reference)

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English

2-Diphenylphosphinobenzaldehyde Usage And Synthesis

Uses	suzuki reaction
Synthesis Reference(s)	Synthetic Communications, 22, p. 1453, 1992 DOI: 10.1080/00397919208021613
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand

2-Diphenylphosphinobenzaldehyde Preparation Products And Raw materials

Raw materials	Phosphine, [2-(1,3-dioxolan-2-yl)phenyl]diphenyl--->Phosphine, diphenyl(trimethylstannyl)--->O-(DIPHENYLPHOSPHINO)BENZONITRILE-->2-BROMOPHENYLDIPHENYLPHOSPHINE-->2-(2-BROMOPHENYL)-1,3-DIOXOLANE-->N,N-DIETHYLBENZAMIDE-->Diphenylphosphine-->2-Bromobenzaldehyde-->2-Bromobenzonitrile-->Chlorodiphenylphosphine
Preparation Products	Diphenylphosphinostyrene-->[S(R)]-N-[(S)-[2-(Diphenylphosphino)phenyl]phenylmethyl]-2-methyl-2-propanesulfinamide

Tag:2-Diphenylphosphinobenzaldehyde(50777-76-9) Related Product Information

tert-Butylchlorodiphenylsilane 4-Hydroxybenzaldehyde Chlorodiphenylphosphine Diphenylphosphine p-Anisaldehyde 2-Nitrobenzaldehyde 4-Dimethylaminobenzaldehyde Benzaldehyde 3-(METHOXYMETHOXY)BENZALDEHYDE (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 2-(Diphenylphosphino)benzoic acid (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Phenyl phosphine 1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 2-Diphenylphosphinobenzaldehyde