1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)-

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1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Suppliers list
Company Name: Shanghai Haohong Pharmaceutical Co., Ltd.  
Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Products Intro: Product Name:(2S,3aR,5S,7aR)-7a-Methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide
CAS:2269472-43-5
Purity:98%
Company Name: Merck KGaA  
Tel: 21-20338288
Email: ordercn@merckgroup.com
Products Intro: Product Name:(+)-PI Reagent
CAS:2269472-43-5
1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Basic information
Product Name:1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)-
Synonyms:1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)-;(2S,3aR,5S,7aR)-7a-Methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide;(+)-PI Reagent
CAS:2269472-43-5
MF:C16H16F5OPS3
MW:446.46
EINECS:
Product Categories:
Mol File:2269472-43-5.mol
1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Structure
1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Chemical Properties
Melting point 119-124°C
Boiling point 423.5±55.0 °C(Predicted)
density 1.46±0.1 g/cm3(Predicted)
form crystals
InChI1S/C16H16F5OPS3/c1-7(2)8-4-5-16(3)9(6-8)25-23(24,22-16)26-15-13(20)11(18)10(17)12(19)14(15)21/h8-9H,1,4-6H2,2-3H3/t8-,9+,16+,23/m0/s1
InChIKeyCZCFCQOKUBIPHN-DWBMIXFYSA-N
SMILESFc1c(c(c(c(c1F)F)S[P]2(=S)S[C@H]3[C@](O2)(CC[C@@H](C3)C(=C)C)C)F)F
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
MSDS Information
1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Usage And Synthesis
Uses(+)-PI Reagent is an air- and moisture-tolerant, reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides. The enantiomer, (−)-PI Reagent, is also available.
Learn more about PI and PSI reagents
1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)- Preparation Products And Raw materials
Tag:1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aR,5S,7aR)-(2269472-43-5) Related Product Information
1,3,2-Benzoxathiaphosphole, hexahydro-3a-methyl-6-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2R,3aR,6S,7aR)- 1,3,2-Benzoxathiaphosphole, hexahydro-3a-methyl-6-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2S,3aS,6R,7aS)- 1,3,2-Benzoxathiaphosphole, hexahydro-7a-methyl-5-(1-methylethenyl)-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide, (2R,3aS,5R,7aS)- 1,3,2-Benzoxathiaphosphole, hexahydro-2-[(2,3,4,5,6-pentafluorophenyl)thio]-, 2-sulfide