5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate

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5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate Basic information
Product Name:5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate
Synonyms:5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate;Benzoxazolium, 5,7-bis(1,1-dimethylethyl)-3-phenyl-, tetrafluoroborate(1-) (1:1);5,7-Di-tert-butyl-3-phenylbenzo [D] oxazole-3-onium Tetrafluoroborate;5,7-ditert-butyl-3-phenyl-1,3-benzoxazol-3-ium;5,7-Di-tert-butyl-3-phenylbenzoxazol-3-ium Tetrafluoroborate;5,7-di-tert-butyl-3-phenyl-1,3λ?-benzoxazol-3-ylium;5,7-ditert-butyl-3-phenylbenzenebenzo[d]azole-3-tetrafluoroboronic acidsalt;5,7-ditert-butyl-3-phenyl-1,3-benzoxazol-3-ium tetrafluoroborate
CAS:1207294-92-5
MF:C21H26BF4NO
MW:395.25
EINECS:
Product Categories:
Mol File:1207294-92-5.mol
5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate Structure
5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate Chemical Properties
Melting point 215-219°C
storage temp. Store at room temperature
form powder
AppearanceWhite to off-white Solid
InChIInChI=1S/C21H26NO.BF4/c1-20(2,3)15-12-17(21(4,5)6)19-18(13-15)22(14-23-19)16-10-8-7-9-11-16;2-1(3,4)5/h7-14H,1-6H3;/q+1;-1
InChIKeyLTQHJVRMJMLRML-UHFFFAOYSA-N
SMILES[B+3]([F-])([F-])([F-])[F-].C(C1C=C(C(C)(C)C)C=C2[N+](C3C=CC=CC=3)=COC=12)(C)(C)C
Safety Information
RIDADR UN1759
WGK Germany WGK 3
HazardClass 8
Storage Class11 - Combustible Solids
MSDS Information
5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate Usage And Synthesis
UsesDeoxazole is an N-heterocyclic carbene salt which activates free alcohols for a C-C cross coupling reaction with aryl halides. The MacMillan group developed a mild, robust, and selective metallaphotoredox-based cross-coupling platform for the deoxygenative coupling for free alcohols using Deoxazole, a Ni catalyst, and [Ir(dtbbpy)(ppy)2]PF6.
5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate Preparation Products And Raw materials
Tag:5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate(1207294-92-5) Related Product Information
Benzoxazolium, 5,7-bis(1,1-dimethylethyl)-3-(3,5-dimethylphenyl)-, tetrafluoroborate 5,7-Di-tert-butyl-3-(4-(trifluoromethyl)phenyl)benzo[d]oxazol-3-ium tetrafluoroborate Benzoxazolium, 3-(4-chlorophenyl)-5,7-bis(1,1-dimethylethyl)-, tetrafluoroborate(1-) (1:1) 5,7-Di-tert-butyl-3-(4-methoxyphenyl)benzo[d]oxazol-3-ium tetrafluoroborate Benzoxazolium, 5,7-bis(1,1-dimethylethyl)-3-[4-(trifluoromethoxy)phenyl]-, tetrafluoroborate(1-) (1:1) Benzoxazolium, 5,7-bis(1,1-dimethylethyl)-3-(3-fluorophenyl)-, tetrafluoroborate(1-) (1:1)