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| | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] Basic information |
| Product Name: | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] | | Synonyms: | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen];RuCl2[(R)(DMSEGPHOS)][(R,(R))(DPEN)];RUCL2[(R)-(DM-SEGPHOS)][(R,(R))-(DPEN)];RuCl2[(R)-dm-segphos(regR)][(R,R)-dpen];Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos(R)][(R,R)-dpen];RuCl2[(R)-dm-segphos(regR)][(R,R)-dpen] RuCl2[(R)-dm-segphos][(R,R)-dpen];RuCl[(R)-dm-segphos][(R,R)-dpen];RuCl2[(R)?(DM?SEGPHOS?)][(R,(R))?(DPEN)] | | CAS: | 944450-45-7 | | MF: | C60H60Cl2N2O4P2Ru | | MW: | 1107.05 | | EINECS: | | | Product Categories: | | | Mol File: | 944450-45-7.mol | ![Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] Structure](CAS/20180808/GIF/944450-45-7.gif) |
| | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] Chemical Properties |
| storage temp. | 2-8°C | | form | Powder | | color | yellow | | Sensitive | air sensitive | | InChIKey | FOEKPXQPRAIJRW-ODQAEMFESA-L | | SMILES | Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10 |
| WGK Germany | 3 | | HS Code | 2843.90.0000 | | Storage Class | 13 - Non Combustible Solids |
| | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] Usage And Synthesis |
| Uses | RuCl2[(R)-(DM-SEGPHOS)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure. |
| | Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] Preparation Products And Raw materials |
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