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Product Name:N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB CAS:1384974-37-1 Package:1g;250mg;5g
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| | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Basic information | | Reaction |
| Product Name: | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB | | Synonyms: | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB;(S,S)-Ts-DENEB(regR);(S,S)-TS-DENEB;(S,S)-Ts-DENEB®N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM);(S,S)-Ts-DENEB[R];(S,S)-Ts-DENEB(regR) (S,S)-Ts-DENEB;Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) | | CAS: | 1384974-37-1 | | MF: | C31H28ClN2O3RuS | | MW: | 645.16 | | EINECS: | | | Product Categories: | | | Mol File: | 1384974-37-1.mol | ![N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Structure](CAS/20211123/GIF/1384974-37-1.gif) |
| | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Chemical Properties |
| storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | solid | | color | gray to brown | | Sensitive | air sensitive |
| RIDADR | UN 3077 9/PG III | | WGK Germany | WGK 3 | | HS Code | 2843.90.0000 | | HazardClass | 9 | | PackingGroup | III | | Storage Class | 11 - Combustible Solids |
| | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Usage And Synthesis |
| Reaction | 1. Catalyst used for asymmetric -transfer hydrogenation.
2. Catalyst used for asymmetric H2 – hydrogenation.
3. Catalyst used for dynamic kinetic resolution.
| | Uses | (S,S)-Ts-DENEB (regR) (CAS# 1384974-37-1) is a catalyst used in transfer hydrogenation reactions, such as in the selective asymmetric transfer hydrogenation of α-substituted acetophenones, and asymmetric transfer hydrogenation of aryl N-heteroaryl ketones. | | reaction suitability | reagent type: ligand |
| | N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Preparation Products And Raw materials |
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