DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

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Products Intro: CAS:12148-71-9
Purity:99% Package:1G;10G;100G;500g;1kg;5kg;10kg;25kg
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CAS:12148-71-9
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Products Intro: Product Name:(1,5-cyclooctadiene)(methoxy)iridium(I) dimer
CAS:12148-71-9
Purity:98% Min. Package:1G;1KG;100KG
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Products Intro: Product Name:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
CAS:12148-71-9
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Products Intro: Product Name:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
CAS:12148-71-9
Purity:98% Package:10MG;50MG;100MG,1G,5G,10G

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Basic information
Description
Product Name:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I);Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%;[Ir(OMe)(1,5-cod)]2;BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII;[Ir(OMe)(1;5-cod)]2;(1,5-Cyclooctadiene)(methoxy)iridium dimer;Bis(1,5-cyclooctadiene)dimethoxydiiridium
CAS:12148-71-9
MF:C18H22Ir2O2
MW:654.81
EINECS:628-411-6
Product Categories:organometallic complex;Metal Catalysts;Ir
Mol File:12148-71-9.mol
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Structure
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties
Melting point 154-179 °C (D)
storage temp. -20°C
form Powder
color yellow
Sensitive Light, Air & Moisture Sensitive
InChIInChI=1S/2C8H8.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H2;2*1H3;;/q;;2*-1;2*+1
InChIKeyWLPGZWOTJGJODI-SXGOCSEPSA-N
SMILESC[O-]1[Ir+]234(C5CCC2=C3CCC4=5)[O-](C)[Ir+]2341C1CCC2=C3CCC4=1
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
TSCA No
HS Code 2843909000
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Usage And Synthesis
DescriptionDI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.
Chemical Propertiesyellow solid
UsesMethoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.
reaction suitabilitycore: iridium
reagent type: catalyst
reaction type: C-H Activation
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials
Tag:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)(12148-71-9) Related Product Information
Phenylboronic acid CHLOROETHANE Tetrahydrofuran Hexane 1-Propanol Glycerol 1,2-Dibromoethane 1,10-Phenanthroline hydrate DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Iridium 1,5-Cyclooctadiene