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Rhodium (triphenylphosphine)carbonylacetylacetonate

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CAS:25470-96-6
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Rhodium (triphenylphosphine)carbonylacetylacetonate manufacturers

Rhodium (triphenylphosphine)carbonylacetylacetonate Basic information
Reaction
Product Name:Rhodium (triphenylphosphine)carbonylacetylacetonate
Synonyms:ACETYLACETONATOCARBONYLTRIPHENYLPHOSPHINERHODIUM (L);Carbonyl-2,4-pentanedionato(triphenylphosphine)rhodium(I), Rh 21%;Acetylacetonatocarbonyltriphenylphosphinerhodium(I) ROPAC Major commercial hydroformylation catalyst;(Z)-4-oxo-2-penten-2-olate;Carbonyl(acetylacetonato)(triphenylphosphine)rhodium(I), 99%;Acetylacetonatocarbonyltriphenylphosphinerhodium(I) ROPAC Major commercial hydrof;ROPAC;Acetylacetonatocarbo
CAS:25470-96-6
MF:C24H23O3PRh
MW:493.32
EINECS:247-015-0
Product Categories:chemical reaction,pharm,electronic,materials;Rh
Mol File:25470-96-6.mol
Rhodium (triphenylphosphine)carbonylacetylacetonate Structure
Rhodium (triphenylphosphine)carbonylacetylacetonate Chemical Properties
Melting point 200-204°C
density 1.5[at 20℃]
vapor pressure 0Pa at 25℃
solubility Soluble in acetone and chlorinated solvents
form solid
color yellow
Water Solubility 24μg/L at 20℃
Merck 14,356
Exposure limitsACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
InChIInChI=1S/C18H15P.C5H7O2.CO.Rh/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4(6)3-5(2)7;1-2;/h1-15H;3H,1-2H3;;/q;-1;;/p+1
InChIKeyZETXURAVPSJSPU-UHFFFAOYSA-O
SMILESP(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Rh+]1(O=C(C)[CH-]C(C)=O1)C#O
EPA Substance Registry SystemRhodium, carbonyl(2,4-pentanedionato-.kappa.O,.kappa.O')(triphenylphosphine)-, (SP-4-2)- (25470-96-6)
Safety Information
Hazard Codes Xi
WGK Germany WGK 3
TSCA TSCA listed
HS Code 28439000
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
ALFA English
Rhodium (triphenylphosphine)carbonylacetylacetonate Usage And Synthesis
ReactionRhodium catalyzed addition of fluorinated acid chlorides to alkynes Reactions of 25470-96-6
Chemical PropertiesYellow Powder
UsesHydroformylation
Flammability and ExplosibilityNot classified
Rhodium (triphenylphosphine)carbonylacetylacetonate Preparation Products And Raw materials
Tag:Rhodium (triphenylphosphine)carbonylacetylacetonate(25470-96-6) Related Product Information
VANADIUM(III) ACETYLACETONATE Vanadyl acetylacetonate Ferric acetylacetonate Cyclopentane Acetylacetone Pentane 1,1,1-Trifluoro-2,4-pentanedione Manganic acetylacetonate Cobaltic acetylacetonate Aluminum acetylacetonate Triphenylphosphine CERIUM ACETYL ACETONATE Tris(triphenylphosphine)chlororhodium Rhodium ZINC ACETYLACETONATE HYDRATE Bis(acetylacetonato)cobalt Titanium(IV)oxide acetylacetonate Magnesium acetylacetonate dihydrate