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1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Suppliers list
Company Name: Shanghai Zhuangming Biopharma Co., Ltd.
Tel:
Email: inquiry@zmsilane.com
Products Intro: Product Name:1,2-Bis(Trimethylsilyloxy)Cyclobutene
CAS:17082-61-0
Purity:99% Package:1KG;USD
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-2158073036
Email: info@dakenam.com
Products Intro: Product Name:1,2-Bis(trimethylsilyloxy)cyclobutene
CAS:17082-61-0
Purity:99% Package:1KG,5KG,10KG
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
Email: ivan@atkchemical.com
Products Intro: Product Name:bis(trimethylsiloxy)cyclobutene
CAS:17082-61-0
Purity:98% HPLC Package:5G;10G;25G;50G;100G;250G;1KG
Company Name: career henan chemical co
Tel: +86-0371-86658258 +8613203830695
Email: sales@coreychem.com
Products Intro: Product Name:1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
CAS:17082-61-0
Purity:99% Package:1KG;1USD
Company Name: Win-Win Chemical CO., Limited
Tel: 0086-577-64498589
Email: sales@win-winchemical.com
Products Intro: Product Name:bis(trimethylsiloxy)cyclobutene
CAS:17082-61-0
Purity:98% Package:1kg,5kg,10kg

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE manufacturers

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Basic information
Product Name:1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
Synonyms:1,2-Bis(triMethylsiloxy)cyclobutene >=95%;4-methoxy-2-vinylbenzenamine ≥2-Chloro-1,3-thiazole ≥2,6-diethylpyridine ≥3-Bromo-5-ethyl-2-methylpyridine ≥(4-Methyl-1,3-thiazol-2-yl)methanol ≥Methyl 3-(3-bromophenyl)-3-oxopropanoate ≥tert-Butyl 3-(bromomethyl)pyrrolidine-1-carboxylate &ge
CAS:17082-61-0
MF:C10H22O2Si2
MW:230.45
EINECS:
Product Categories:Cyclobutanes & Cyclobutenes;Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Simple 4-Membered Ring Compounds;Si-O Compounds;Synthetic Organic Chemistry;Enol Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:17082-61-0.mol
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Chemical Properties
Boiling point 58-59 °C2 mm Hg(lit.)
density 0.897 g/mL at 25 °C(lit.)
refractive index n20/D 1.435(lit.)
Fp 142 °F
storage temp. Inert atmosphere,2-8°C
solubility sol hydrocarbons and ethers.
form clear liquid
Specific Gravity0.87
color Colorless to Light yellow
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1367530
InChIInChI=1S/C10H22O2Si2/c1-13(2,3)11-9-7-8-10(9)12-14(4,5)6/h7-8H2,1-6H3
InChIKeyWOBRFSDEZREQAB-UHFFFAOYSA-N
SMILESC1(O[Si](C)(C)C)CCC=1O[Si](C)(C)C
CAS DataBase Reference17082-61-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 1993
WGK Germany 3
10-21
TSCA No
HS Code 2931.90.6000
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses1,2-Bis(trimethylsilyloxy)cyclobutene is a useful chemical reactant used in the preparation and biological activity of serine and threonine β-lactones as inhibitors of hepatitis A virus 3C cysteine proteinase.
ApplicationUsed as a suitable reagent for annulation processes and 4-keto ester synthesis.
General DescriptionPhotocycloaddition of 2-cyclohexenones to 1,2-bis(trimethyl-siloxy)cyclobutene has been studied. It undergoes Aldol condensation reaction with carbonyl compounds. It reacts with Br2 to give cyclobutanedione.
Synthesis1,2-Bis(trimethylsilyloxy)cyclobutene is prepared as a colorless liquid by acyloin condensation of Diethyl Succinate (dispersed Na in toluene or Et2O, reflux) using Chlorotrimethylsilane as trapping agent.
storageUse in a fume hood; the compound is stable for years if stored in a tightly screw-capped bottle. Prolonged exposure to moist air leads to decomposition.
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Preparation Products And Raw materials
Preparation Products2-(benzyloxy)cyclobutan-1-one-->2-Methyl-1,3-cyclopentanedione-->3-HYDROXY-2-PHENYLCYCLOPENT-2-ENONE
Tag:1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE(17082-61-0) Related Product Information
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