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Product Name:TRI-N-BUTYLGERMANE
CAS:998-39-0
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| | TRI-N-BUTYLGERMANE Basic information |
| | TRI-N-BUTYLGERMANE Chemical Properties |
| Melting point | <0°C | | Boiling point | 123 °C/20 mmHg (lit.) | | density | 0.949 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.45(lit.) | | Fp | >230 °F | | solubility | Not miscible. | | form | Liquid | | Specific Gravity | 0.92 | | Sensitive | Air & Moisture Sensitive | | InChI | InChI=1S/C12H28Ge/c1-4-7-10-13(11-8-5-2)12-9-6-3/h13H,4-12H2,1-3H3 | | InChIKey | KTSWILXIWHVQLR-UHFFFAOYSA-N | | SMILES | [GeH](CCCC)(CCCC)CCCC | | CAS DataBase Reference | 998-39-0(CAS DataBase Reference) |
| | TRI-N-BUTYLGERMANE Usage And Synthesis |
| Chemical Properties | clear colorless liquid | | Chemical Properties | Reduces acid chlorides to aldehydes in presence of
Pd(0). Effects free-radical reductive addition of alkyl
halides to olefins. Reduces benzylic chlorides 70x faster
than silyl hydrides. | | Uses | Efficient reducing agent for benzylic chlorides.1 | | Uses | Tri-n-butylgermanium hydride is used in the reduction of benzylic chlorides. It is also used as pharmaceutical intermediate. | | General Description | Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail. | | reaction suitability | core: germanium
reagent type: reductant |
| | TRI-N-BUTYLGERMANE Preparation Products And Raw materials |
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