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2-Methyl-4-phenyl-1H-imidazole

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Products Intro: Product Name:2-Methyl-4-phenyl-1H-imidazole
CAS:13739-48-5
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Products Intro: Product Name:2-Methyl-4-phenyl-1H-imidazole
CAS:13739-48-5
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Factory Supply
2-Methyl-4-phenyl-1H-imidazole Basic information
Product Name:2-Methyl-4-phenyl-1H-imidazole
Synonyms:2-METHYL-4-PHENYL-1H-IMIDAZOLE;1H-imidazole, 2-methyl-4-phenyl-;2-methyl-4-phenyl-1H-imidazole(SALTDATA: FREE);4-(2-Methyl Phenyl)IMidazole;2-Methyl-5-phenyliMidazole;2-methyl-4-phenyl-3H-imidazole;2-Methyl-4-phenylimidazole;1H-Imidazole, 2-methyl-5-phenyl-
CAS:13739-48-5
MF:C10H10N2
MW:158.2
EINECS:
Product Categories:Imidazoles & Benzimidazoles
Mol File:13739-48-5.mol
2-Methyl-4-phenyl-1H-imidazole Structure
2-Methyl-4-phenyl-1H-imidazole Chemical Properties
Melting point 159-160.5 °C
Boiling point 396.2±11.0 °C(Predicted)
density 1.109±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka14.13±0.10(Predicted)
AppearanceWhite to light yellow Solid
Safety Information
Risk Statements 36
Safety Statements 26
HazardClass IRRITANT
HS Code 2933299090
MSDS Information
2-Methyl-4-phenyl-1H-imidazole Usage And Synthesis
Synthesis
Acetamide, N-[2-(4-fluorophenyl)-2-oxoethyl]-

451-50-3

2-Methyl-4-phenyl-1H-imidazole

13739-48-5

Using stilbene (150 mL) as solvent, benzoylacetamide (10.15 mmol), ammonium acetate (64.86 mmol) and acetic acid (166.6 mmol) were added and the mixture was heated to reflux and azeotropized to remove the water, and the reaction lasted for 6 hours. Upon completion of the reaction, the reaction mixture was cooled to room temperature and washed with 25 mL of water followed by distillation to remove the solvent to give the crude product. The crude product was purified by column chromatography using silica gel (60-120 mesh) as stationary phase and a solvent mixture of dichloromethane and methanol (100:5, v/v) as mobile phase to give the final target compound 2-methyl-4-phenyl-1H-imidazole.

References[1] Patent: WO2009/137081, 2009, A2. Location in patent: Page/Page column 49-51
2-Methyl-4-phenyl-1H-imidazole Preparation Products And Raw materials
Raw materialsAcetamide, N-[2-(4-fluorophenyl)-2-oxoethyl]--->Xylene-->Acetic acid-->Ammonium acetate
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