Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V)

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Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V) Basic information
Product Name:Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V)
Synonyms:Trichloro[methylenebis[diphenylphosphine]-P,P′]oxorhenium;Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V)
CAS:60260-17-5
MF:C25H22Cl3OP2Re
MW:692.96
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhenium
Mol File:Mol File
Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V) Structure
Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V) Chemical Properties
form solid
InChI1S/C25H22P2.3ClH.O.Re/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;;/h1-20H,21H2;3*1H;;/q;;;;;+3/p-3
InChIKeySAVOOVLDSRTAGJ-UHFFFAOYSA-K
SMILESCl[Re](Cl)(Cl)=O.C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
Safety Information
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V) Usage And Synthesis
UsesCatalyst for:
  • Epoxidation of olefins using hydrogen peroxide activated bicarbonate as an oxidant
  • Efficient reduction of aromatic sulfoxides
  • Regioselective coupling of propargyl alcohols with sulfonamides and carbamates
  • Cycloisomerization reactions
reaction suitabilitycore: rhenium
reagent type: catalyst
Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V) Preparation Products And Raw materials
Tag:Oxotrichloro(bis(diphenylphosphino)methane)rhenium(V)(60260-17-5) Related Product Information
Bis(diphenylphosphino)methane