3-AMINO-3-METHYL-BUTAN-1-OL

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CAS:42514-50-1
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CAS:42514-50-1
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3-AMINO-3-METHYL-BUTAN-1-OL Basic information
Uses
Product Name:3-AMINO-3-METHYL-BUTAN-1-OL
Synonyms:3-AMINO-3-METHYL-BUTAN-1-OL;3-Amino-3-methyl-1-butanol;3-Amino-3-methyl-butan-I-ol;1-butanol, 3-amino-3-methyl-;1-hydroxy-3-methylbut-3-ylamine
CAS:42514-50-1
MF:C5H13NO
MW:103.16
EINECS:255-865-9
Product Categories:pharmacetical
Mol File:42514-50-1.mol
3-AMINO-3-METHYL-BUTAN-1-OL Structure
3-AMINO-3-METHYL-BUTAN-1-OL Chemical Properties
Boiling point 71 °C(Press: 9 Torr)
density 0.8380 g/cm3
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka15.42±0.10(Predicted)
AppearanceColorless to light yellow Liquid
Safety Information
RIDADR 2735
HazardClass 8
PackingGroup 
MSDS Information
3-AMINO-3-METHYL-BUTAN-1-OL Usage And Synthesis
Uses3-Amino-3-methylbut-1-ol can be used as a pharmaceutical synthesis intermediate.
Synthesis
1-Butanol, 3-methyl-3-[(phenylmethyl)amino]-

17945-55-0

3-AMINO-3-METHYL-BUTAN-1-OL

42514-50-1

Step 3 Synthesis of 3-amino-3-methyl-1-butanol: 3-benzylamino-3-methyl-1-butanol (3.86 g, 20.0 mmol) was dissolved in ethanol (80 mL) and 10% palladium carbon catalyst (400 mg) was added. The reaction mixture was stirred for 6 hours at room temperature under hydrogen atmosphere (5 kgf/cm2). Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under vacuum. The residue was purified by distillation to afford the colorless oily product 3-amino-3-methyl-1-butanol (2.00 g, 97% yield). The structure of the product was confirmed by 1H-NMR (400 MHz, CDCl3): δ1.21 (6H, s), 1.59 (2H, t, J=5.5 Hz), 2.63-2.76 (3H, br), 3.85 (2H, t, J=5.5 Hz).

References[1] Patent: US2007/254866, 2007, A1. Location in patent: Page/Page column 102
3-AMINO-3-METHYL-BUTAN-1-OL Preparation Products And Raw materials
Raw materials1-Butanol, 3-methyl-3-[(phenylmethyl)amino]--->4H-1,3-Oxazine, 5,6-dihydro-2,4,4-trimethyl--->Hydrogen-->Ethanol
Tag:3-AMINO-3-METHYL-BUTAN-1-OL(42514-50-1) Related Product Information
2,2,5,5-TETRAMETHYL-3-PYRROLIN-1-OXYL-3-CARBOXYLIC ACID N-HYDROXYSUCCINIMIDE ESTER 2,4,4,6-TETRAMETHYL-1-OXA-3-AZA-2-CYCLOHEXENE 4-Hydroxy-2,2,6,6-tetramethyl-piperidinooxy 5,6-DIHYDRO-2-PHENYL-4,4,6-TRIMETHYL-1,3(4H)-OXAZINE CEPHALOTAXINE HARRINGTONINE 3-Carboxy-2,2,5,5-tetraMethylpyrrolidine 1-Oxyl Free Radical EUCATROPINE HYDROCHLORIDE (2S)-2-AMINO-3-METHYL-BUTAN-1-OL,(S)-2-AMINO-3-METHYL-BUTAN-1-OL 3-Methyl-1-butanol 2,2,6,6-Tetramethyl-4-piperidinol 3-(4-NITROPHENOXYCARBONYL)-2,2,5,5-TETRAMETHYL-1-PYRROLIDINYLOXY 2-BENZYL-5,6-DIHYDRO-4,4,6-TRIMETHYL-1,3(4H)-OXAZINE 2-AMINO-2-METHYLSUCCINIC ACID 4-ETHOXYFLUOROPHOSPHINYLOXY TEMPO 3-[(ETHOXYCARBONYL)OXYCARBONYL]-2,5-DIHYDRO-2,2,5,5-TETRAMETHYL-1H-PYRROL-1-YLOXY 1-Amino-3-methyl-butan-2-ol 3-amino-2-methyl-butan-2-ol

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