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Diphenyl sulfone

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CAS:127-63-9
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Diphenyl sulfone Basic information
Product Name:Diphenyl sulfone
Synonyms:Benzene, 1,1'-sulfonylbis-;Difenylsulfon;dlphenylsulfone;phenylsulphone;s-127;s-97;Sulfone, diphenyl;Diphenylsulfone,99%
CAS:127-63-9
MF:C12H10O2S
MW:218.27
EINECS:204-853-1
Product Categories:Flexibilizer,acaricide and organic synthesis;Biochemistry;Color Former & Related Compounds;Diphenyl Sulfones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;Reagents for Oligosaccharide Synthesis;Sensitizer;127-63-9
Mol File:127-63-9.mol
Diphenyl sulfone Structure
Diphenyl sulfone Chemical Properties
Melting point 123-129 °C (lit.)
Boiling point 379 °C (lit.)
density 1.36
vapor pressure 0.001Pa at 50℃
refractive index 1.5200 (estimate)
Fp 184°C
storage temp. Sealed in dry,Room Temperature
solubility >14mg/l
form Crystalline Powder
color White
Water Solubility insoluble
Merck 14,3332
BRN 1910573
Major Applicationagriculture
environmental
InChI1S/C12H10O2S/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKeyKZTYYGOKRVBIMI-UHFFFAOYSA-N
SMILESO=S(=O)(c1ccccc1)c2ccccc2
LogP2.61
CAS DataBase Reference127-63-9(CAS DataBase Reference)
NIST Chemistry ReferenceDiphenyl sulfone(127-63-9)
EPA Substance Registry SystemDiphenylsulfone (127-63-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
RTECS SX2400000
TSCA TSCA listed
HS Code 29309070
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
ToxicityLD50 orally in rats: >2 g/kg, Residue Rev. 36, 240 (1971)
MSDS Information
ProviderLanguage
Diphenyl sulfone English
SigmaAldrich English
ACROS English
ALFA English
Diphenyl sulfone Usage And Synthesis
Chemical PropertiesDiphenyl sulfone is a sulfone compound having two S-phenyl substituents. It is a crystalline powder that is soluble in organic solvents. It has been found in plants like Gnidia glauca and Dioscorea bulbifera. It has a role as a plant metabolite.
Diphenyl sulfone
Diphenyl sulfone is formed under certain conditions by the action of aqueous sulfuric acid on benzene. It is used as a high temperature solvent. Such high temperature solvents are useful for processing highly rigid polymers, e.g., PEEK, which only dissolve in very hot solvents.
UsesOvicide; acaricide.
UsesDiphenyl sulfone was identified as the preferred solvent. Diphenyl sulfone is chemically and thermally stable as compared to dimethyl sulfoxide.
UsesPhenyl Sulphone undergoes deoxygenation with Mg-MeOH at room temperature.
DefinitionChEBI: A sulfone compound having two S-phenyl substituents. It has been found in plants like Gnidia glauca and Dioscorea bulbifera.
Synthesis Reference(s)The Journal of Organic Chemistry, 50, p. 1784, 1985 DOI: 10.1021/jo00210a053
Synthesis, p. 342, 1974
Tetrahedron Letters, 21, p. 689, 1980 DOI: 10.1016/S0040-4039(00)71446-8
Flammability and ExplosibilityNot classified
PreparationDiphenyl sulfone is produced by the sulfonation of benzene with sulfuric acid and oleum. It is also produced from benzenesulfonyl chloride and benzene.
Purification MethodsCrystallise the sulfone from diethyl ether. It has been purified by zone melting. [Beilstein 6 H 300, 6 IV 1490.]
Tag:Diphenyl sulfone(127-63-9) Related Product Information
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