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| | 3,3-Dimethylallyl bromide Basic information |
| | 3,3-Dimethylallyl bromide Chemical Properties |
| Melting point | -106.7°C (estimate) | | Boiling point | 82-83 °C150 mm Hg(lit.) | | density | 1.29 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.489(lit.) | | Fp | 88 °F | | storage temp. | 2-8°C | | form | Liquid | | color | Clear colorless, yellow or brown | | Specific Gravity | 1.27 | | Water Solubility | Immiscible with water | | Sensitive | Light Sensitive | | BRN | 1420778 | | InChI | 1S/C5H9Br/c1-5(2)3-4-6/h3H,4H2,1-2H3 | | InChIKey | LOYZVRIHVZEDMW-UHFFFAOYSA-N | | SMILES | C\C(C)=C\CBr | | CAS DataBase Reference | 870-63-3(CAS DataBase Reference) | | NIST Chemistry Reference | 2-Butene, 1-bromo-3-methyl-(870-63-3) | | EPA Substance Registry System | 2-Butene, 1-bromo-3-methyl- (870-63-3) |
| Hazard Codes | C,F | | Risk Statements | 10-34-20/21/22-11 | | Safety Statements | 26-36/37/39-45-16 | | RIDADR | UN 2920 8/PG 2 | | WGK Germany | 3 | | F | 8-10-19-23 | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29033990 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B |
| | 3,3-Dimethylallyl bromide Usage And Synthesis |
| Chemical Properties | 3,3-Dimethylallyl bromide is colourless liquid | | Uses | 3,3-Dimethylallyl bromide is a useful source of the 3,3-dimethylallyl or prenyl group for the synthesis of natural products1 and in the synthesis of base-modified pyrimidine nucleosides.2 | | Uses | 3,3-Dimethylallyl bromide has been used in the preparation of:
- (±)-eldanolide
- 1-(3,3-dimethylallyl)-L-tryptophan
- (±)-fumagillin, antibiotic isolated from Aspergillus fumigattus
| | Uses | 3,3-Dimethylallyl bromide was used in the synthesis of 1- and 2-allylic-3-methylindoles. It was also used in the synthesis of products and base-modified pyrimidine nucleosides. |
| | 3,3-Dimethylallyl bromide Preparation Products And Raw materials |
| Preparation Products | Azetidine-->4-(Dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran-->1,1,7,7-TETRAMETHYL-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-IJ]QUINOLINE-9-CARBALDEHYDE-->1,1,7,7-TETRAMETHYLJULOLIDINE-->1,2,3,4-Tetrahydro-4,4-dimethylquinoline ,95%-->4-METHYL-3-PENTENOIC ACID-->2-METHYLOCTANE-->Licoflavone C-->2,2-dimethylbut-3-enoic acid-->NERYL ACETATE |
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