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Tetrahydrofurfuryl methacrylate

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Products Intro: Product Name:Tetrahydrofurfuryl methacrylate
CAS:2455-24-5
Purity:99.0% Package:200kg
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CAS:2455-24-5
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Tetrahydrofurfuryl methacrylate Basic information
Product Name:Tetrahydrofurfuryl methacrylate
Synonyms:METHACRYLIC ACID TETRAHYDROFURFURYL ESTER;2-METHYL-ACRYLIC ACID TETRAHYDRO-FURAN-2-YLMETHYL ESTER;TETRAHYDROFURFURYL METHACRYLATE;(TETRAHYDRO-2-FURANYL)METHYLMETHACRYLATE;2-methyl-2-propenoicaci(tetrahydro-2-furanyl)methylester;2-Propenoicacid,2-methyl-,(tetrahydro-2-furanyl)methylester;sartomersr203;sr203
CAS:2455-24-5
MF:C9H14O3
MW:170.21
EINECS:219-529-5
Product Categories:FuransMonomers;Acrylic Monomers;Building Blocks;Heterocyclic Building Blocks;Methacrylate
Mol File:2455-24-5.mol
Tetrahydrofurfuryl methacrylate Structure
Tetrahydrofurfuryl methacrylate Chemical Properties
Boiling point 52 °C0.4 mm Hg(lit.)
density 1.044 g/mL at 25 °C(lit.)
vapor pressure 27Pa at 20℃
refractive index n20/D 1.458(lit.)
Fp 195 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form clear liquid
Specific Gravity1.044
color Colorless to Almost colorless
Water Solubility 18.99g/L at 20℃
Sensitive Light Sensitive
BRN 117423
Cosmetics Ingredients FunctionsFILM FORMING
InChI1S/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKeyLCXXNKZQVOXMEH-UHFFFAOYSA-N
SMILESCC(=C)C(=O)OCC1CCCO1
LogP1.76 at 22.6℃
CAS DataBase Reference2455-24-5(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester(2455-24-5)
EPA Substance Registry SystemTetrahydrofurfuryl methacrylate (2455-24-5)
Safety Information
Risk Statements 10-36/37/38
Safety Statements 36
RIDADR 3272
WGK Germany 1
TSCA TSCA listed
HazardClass 3
PackingGroup III
HS Code 29321900
Storage Class10 - Combustible liquids
Hazardous Substances Data2455-24-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Tetrahydrofurfuryl methacrylate Usage And Synthesis
DescriptionTetrahydrofurfuryl methacrylate (THFMA) is derived from renewable resources and is obtained by chemical modification of furfural produced from hemicellulose. THFMA was used as a biobased reactive diluent that reduces the viscosity of AESO in DLP 3D printing. According to stress relaxation tests, THFMA was found to be a suitable monomer in the UV-curing of HPPA and AESO because the formed dynamic networks could rapidly undergo thermoactivated network topology rearrangements. The addition of THFMA to the resins contributed to weldability, repairability, shape memory, and reprocessability properties[2].
Chemical PropertiesColorless liquid
UsesTetrahydrofurfuryl methacrylate is used as methacrylic component in dental materials, such as crown and bridge products; in artificial nails.
DefinitionChEBI: Tetrahydrofurfuryl methacrylate is a member of oxolanes.
Application Tetrahydrofurfuryl Methacrylate (THFMA) is a clear water white to light yellow liquid. It has a 2.84 cps viscosity at 20°C. Poly(tetrahydro furfuryl methacrylate) [P(THFMA)] has been investigated as a biomaterial for encouraging articular cartilage repair because it possesses some unique characteristics with respect to its biocompatibility and behavior in water. Furthermore, its monomer was used as a tissue repair material[1].
References [1] Sang-Ha Cho, Hun-Soo Byun, Bong-Seop Lee . “Phase behavior of tetrahydrofurfuryl methacrylate and poly(tetrahydrofurfuryl methacrylate) in supercritical carbon dioxide.” Journal of CO2 Utilization 25 (2018): Pages 39-45.
[2] Sigita Grauzeliene . “Biobased vitrimer synthesized from 2-hydroxy-3-phenoxypropyl acrylate, tetrahydrofurfuryl methacrylate and acrylated epoxidized soybean oil for digital light processing 3D printing.” European Polymer Journal 198 (2023): Article 112424.
Tetrahydrofurfuryl methacrylate Preparation Products And Raw materials
Raw materialsTetrahydrofurfuryl alcohol-->Ethyl methacrylate-->Methyl methacrylate-->Methacrylic acid
Tag:Tetrahydrofurfuryl methacrylate(2455-24-5) Related Product Information
Methyl methacrylate Butyl methacrylate Stearyl Methacrylate Tetrahydrofuran Methyl acrylate Methyl propiolate Isobornyl methacrylate 2-Hydroxyethyl methacrylate Methacrylic acid Cyclohexyl methacrylate Poly(methyl methacrylate) Tetrahydrofurfuryl alcohol Tetrahydrofurfuryl acrylate [2-(METHACRYLOYLOXY)ETHYL]TRIMETHYLAMMONIUM METHYL SULFATE METHACRYLOYLAMINOPROPYLTRIMETHYLAMMONIUM METHYL SULFATE 2-(2-OXO-1-IMIDAZOLIDINYL)ETHYL METHACRYLATE Allyl methacrylate 3-Methacryloxypropylmethyldimethoxysilane