[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE

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Products Intro: Product Name:[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE
CAS:79255-71-3
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Products Intro: Product Name:[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE
CAS:79255-71-3
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Products Intro: Product Name:121,4-bis(diphenylphosphine)butane(1,5-cyclooctadiene)rhodium(I)tetrafluoro
CAS:79255-71-3
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Products Intro: Product Name:[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodiu...
CAS:79255-71-3
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Products Intro: Product Name:[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:79255-71-3
Purity:98% Package:$99.9/100mg;$318.9/500mg;Bulk package Remarks:98%

[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE manufacturers
[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE Basic information
Reaction
Product Name:[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE
Synonyms:(1,4-BIS(DIPHENYLPHOSPHINO)BUTANE)(1,5-C YCLOOCTADIENE)RHODIUM(I) BF4, 98%;[bis(diphenylphosphino)butane](cyclooctadiene)rhodium BF4;[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE;1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, dichloromethane adduct, min. 98%;1,4-Bis(diphenylpyhosphino)butane(1,5-cycloocatdiene)rhodiuM(I)tetrafluoroborate,dichloroMethaneadduct,Min.98%;1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, dichloroMethane adduct,98%;[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodiu;[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate 98%
CAS:79255-71-3
MF:C36H40BF4P2Rh
MW:724.36
EINECS:
Product Categories:Rh;organometallic complex;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:79255-71-3.mol
[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE Structure
[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE Chemical Properties
Melting point 205 °C (dec.)(lit.)
form Powder
color orange
Sensitive air sensitive
InChIKeyYESRLRPURJQQBI-ONEVTFJLSA-N
SMILES[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
CAS DataBase Reference79255-71-3
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE Usage And Synthesis
Reaction
  1. Catalyst used in the intramolecular, hydroamination of olefins.
  2. Catalyst used for reductive aminations.
Reactions of 79255-71-3
Uses[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the:
  • Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine.
  • Enantioselective reductive amination of α-ketoacids with benzylamines to synthesize α-N-benzylamino acids.
  • Stereoselective hydrogenation of α-(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.
reaction suitabilitycore: rhodium
reagent type: catalyst
[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE Preparation Products And Raw materials
Tag:[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE(79255-71-3) Related Product Information
1,5-Cyclooctadiene ACETONE-D6 1,4-Bis(diphenylphosphino)butane BORANE-DIPHENYLPHOSPHINE COMPLEX METHYLPHOSPHINE BORANE COMPLEX 1,4-BIS(DIMETHYLPHOSPHINO)BUTANE [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE