ChemicalBook > Product Catalog >Catalyst and Auxiliary >Precious Metal Catalysts >rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Request For Quotation
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Suppliers list
Company Name: WUXI HONOR SHINE CHEMICAL CO.,LTD
Tel: +86-0510-83593312 +8619805123561
Email: sales@honorshinechem.com
Products Intro: Product Name:Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride
CAS:100163-29-9
Purity:0.98 Package:25KG;5KG
Company Name: RongNa Biotechnology Co.,Ltd
Tel: +86-86-13583358881 +8618560316533
Email: Brad@rongnabiotech.com
Products Intro: Product Name:rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl))zirconium dichloride
CAS:100163-29-9
Purity:99% Package:1ASSAYS;10USD
Company Name: CONIER CHEM AND PHARMA LIMITED
Tel: +8618523575427
Email: sales@conier.com
Products Intro: Product Name:rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl))zirconium dichloride
CAS:100163-29-9
Purity:99% Package:1kg
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196
Email: sale04@alfachem.cn
Products Intro: Product Name:rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
CAS:100163-29-9
Purity:97%min Package:5g;25g;100g;500g;1kg;25kg
Company Name: Career Henan Chemica Co
Tel: +86-0371-86658258 +8613203830695
Email: laboratory@coreychem.com
Products Intro: Product Name:rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
CAS:100163-29-9
Purity:95.0%-99.0% Package:1ASSAYS;6.05USD

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride manufacturers
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Basic information
Stability Storage
Product Name:rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
Synonyms:RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV);RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM;(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV);DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
CAS:100163-29-9
MF:C20H24Cl2Zr10*
MW:426.53
EINECS:202-303-5
Product Categories:metallocene;Zr;Catalysis and Inorganic Chemistry;Chemical Synthesis;Zirconium
Mol File:100163-29-9.mol
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Structure
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties
Melting point 267-271 °C(lit.)
form Powder
color white to pale yellow
Sensitive moisture sensitive
InChIInChI=1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
InChIKeyAKXWJOYQORUUHS-UHFFFAOYSA-L
SMILES[C]12[C]([CH][CH][C]1CCCC2)CC[C]1[CH][CH][C]2CCCC[C]12.[Zr](Cl)Cl |^1:0,1,2,3,4,11,12,13,14,19|
Safety Information
Hazard Codes C,Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-45-36
RIDADR UN 3261 8/PG 2
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Usage And Synthesis
StabilityStable under normal temperature and pressure, avoid contact with water and oxidants.
Storagesealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.
Chemical PropertiesWhite to pale yellow powder,it can carry out catalytic reaction.
UsesRac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.
UsesCatalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines
reaction suitabilitycore: zirconium
reagent type: catalyst
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Preparation Products And Raw materials
Tag:rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride(100163-29-9) Related Product Information
Zirconium tetrachloride Cobalt chloride Dichloroacetic acid POLYETHYLENE, CHLORINATED Zirconium oxychloride Bis(ethylcyclopentadienyl)zirconium dichloride Bis(1-ethyl-2-methylcyclopentadienyl)zirconium dichloride Bis(1-propyl-3-methylcyclopentadienyl)zirconium dichloride BIS(CYCLOPENTADIENYL)ZIRCONIUM DIHYDRIDE Bis(cyclopentadienyl)zirconium dichloride BIS(N-PROPYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE Bis(1-ethyl-3-methylcyclopentadienyl)zirconium dichloride Bis(1-butyl-3-methylcyclopentadienyl)zirconium dichloride ZIRCONYL CHLORIDE HYDRATE Bis(n-butylcyclopentadienyl)zirconium dichloride Zirconium Bis(methylcyclopentadienyl)zirconium dichloride BIS(1,3-DIMETHYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE