- Methyl 2-oxoacetate
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- $9.80
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2019-12-26
- CAS:922-68-9
- Min. Order: 1g
- Purity: ≥99%
- Supply Ability: 100kg
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| | Methyl 2-oxoacetate Basic information |
| Product Name: | Methyl 2-oxoacetate | | Synonyms: | 2-(2-METHOXYPHENOXY)ETHANAMINE HCL;2-(2-METHOXYPHENOXY)ETHYLAMINE HCL;2-(2-METHOXPHENOXYL)ETHYLAMINE MONOHYDROCHLORIDE;2-(2-METHOXPHENOXYL) ETHYLAMINE HCL;2-(METHOXY PHENOXY)ETHYLAMINE HYDROCHLORIDE;GLYOXYLIC ACID METHYL ESTER;Methyl oxoacetate;oxo-aceticacimethylester | | CAS: | 922-68-9 | | MF: | C3H4O3 | | MW: | 88.06 | | EINECS: | 213-084-0 | | Product Categories: | Miscellaneous Reagents | | Mol File: | 922-68-9.mol |  |
| | Methyl 2-oxoacetate Chemical Properties |
| | Methyl 2-oxoacetate Usage And Synthesis |
| Uses | Methyl Glyoxylate is a useful compound for preparation of pyridine and quinoline derivatives. | | Preparation | Preparative Methods of Methyl 2-oxoacetate: efficient methods include oxidative cleavage of tartrate diesters, ozonolysis of
maleate/fumarate derivatives, exchange reaction between appropriate dialkoxyacetate and glyoxylic acid,
and NaOAc-catalyzed elimination of nitrite ion from nitrate esters.[1] | | General Description | Methyl Glyoxylate is a two-carbon synthon utilized in electrocyclic processes (Diels-Alder reaction, ene reactions), various
condensations (Mannich, aldol, Wittig, Prins, acyloin), carbinolamine formation, and Friedel-Crafts
reactions. | | storage | Methyl 2-oxoacetate stores under N2 in a refrigerator due to their tendency to form a
monohydrate and/or polymerize. | | References | 1. (a) Wolf, F. J.; Weijland, J. OSC 1963, 4, 124. (b) Jung, M. E.; Shishido, K.; Davis, L. H. JOC 1982, 47, 891. (c)
Blake, J.; Tretter, J. R.; Juhasz, G. J.; Bonthrone, W.; Rappoport, H. JACS 1966, 88, 4061. (d) Haggerty, J. G.; Kelly,
T. R.; Schmidt, T. E. S 1972, 544. Hook, J. M. SC 1984, 14, 83. (e) Kornblum, N.; Frazier, H. W. JACS 1966, 88, 865. |
| | Methyl 2-oxoacetate Preparation Products And Raw materials |
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