| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
|
| | (S)-Ph-quinox >=95% Basic information |
| Product Name: | (S)-Ph-quinox >=95% | | Synonyms: | (S)-Ph-quinox >=95%;2-[(4S)-4,5-dihydro-4-phenyl-2-
oxazolyl]-Quinoline;(S)-4-phenyl-2-(quinolin-2-yl)-4,5-dihydrooxazole;(S)-Ph-quinox;Quinoline, 2-[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]-;(S)-Ph-quinox | | CAS: | 1252576-13-8 | | MF: | C18H14N2O | | MW: | 274.32 | | EINECS: | | | Product Categories: | | | Mol File: | 1252576-13-8.mol |  |
| | (S)-Ph-quinox >=95% Chemical Properties |
| Melting point | 142°C | | Boiling point | 476.8±38.0 °C(Predicted) | | density | 1.22±0.1 g/cm3(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | powder or crystals | | pka | 3.27±0.61(Predicted) | | Appearance | Off-white to light yellow Solid | | Optical Rotation | Consistent with structure |
| WGK Germany | WGK 3 | | Storage Class | 13 - Non Combustible Solids |
| | (S)-Ph-quinox >=95% Usage And Synthesis |
| Uses | (S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen. | | reaction suitability | reagent type: catalyst reagent type: ligand reaction type: C-H Activation |
| | (S)-Ph-quinox >=95% Preparation Products And Raw materials |
|