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3,4-Diethoxyaniline

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  • Purity: 0.99
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3,4-Diethoxyaniline Basic information
Product Name:3,4-Diethoxyaniline
Synonyms:AKOS BBS-00001416;3,4-DIETHOXYBENZENAMINE;3,4-DIETHOXYANILINE;3,4-diethoxy-phenylamine;Benzenamine, 3,4-diethoxy-;3,4-Diethoxyaniline ISO 9001:2015 REACH
CAS:39052-12-5
MF:C10H15NO2
MW:181.23
EINECS:200-589-5
Product Categories:
Mol File:39052-12-5.mol
3,4-Diethoxyaniline Structure
3,4-Diethoxyaniline Chemical Properties
Melting point 48°C
Boiling point 314.35°C (rough estimate)
density 1.0918 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility soluble in Methanol
pka4.89±0.10(Predicted)
form powder to crystal
color Light yellow to Brown
Safety Information
Hazard Codes Xi
Risk Statements 36
HS Code 2922190090
MSDS Information
3,4-Diethoxyaniline Usage And Synthesis
Chemical PropertiesPink Solid
Uses 3,4-Diethoxyaniline can be used as an intermediate for the fungicide ethofluthrin.
Synthesis
3,4-DIETHOXY NITROBENZENE

4992-63-6

3,4-Diethoxyaniline

39052-12-5

The general procedure for the synthesis of 3,4-diethoxyaniline from 3,4-diethoxynitrobenzene was as follows: 3,4-diethoxynitrobenzene (6.30 g, 29.9 mmol), 10% palladium-carbon catalyst (600 mg), and anhydrous ethanol (300 mL) were added to a reaction flask, and the reaction was stirred for 6 hours under hydrogen atmosphere. Upon completion of the reaction, the insoluble palladium-carbon catalyst was removed by filtration and the filtrate was concentrated under reduced pressure to afford 3,4-diethoxyaniline as an oily product in a yield of 5.02 g (92.9% yield). The product was characterized by 1H-NMR (CDCl3) with chemical shifts δ: 1.34 to 1.46 (6H, m), 3.94 to 4.08 (4H, m), 6.21 (1H, d, J = 2.8,8.4 Hz), 6.30 (1H, d, J = 2.6 Hz), 6.73 (1H, d, J = 8.4 Hz).

References[1] Patent: EP1437344, 2004, A1. Location in patent: Page 37
[2] Yuki Gosei Kagaku Kyokaishi, 1959, vol. 17, p. 166,169
[3] Chem.Abstr., 1959, p. 11280
Tag:3,4-Diethoxyaniline(39052-12-5) Related Product Information
3,4-DIETHOXY NITROBENZENE 4-ACRYLAMIDOBENZO-18-CROWN-6, 98 4-Aminobenzo-15-crown-5 hydrochloride 4-NITROBENZO-15-CROWN-5 4'-Aminobenzo-15-crown-5-ether 3,4-Diethoxyaniline 4-NITROBENZO-18-CROWN-6 N-BENZOYL-2,5-DIETHOXYANILINE 4-Benzamido-2,5-diethoxyaniline,4-BENZOYLAMINO-2,5-DIETHOXYANILINE 4-BENZOYLAMINO-2,5-DIETHOXYANILINE DIAZONIUM SALT Diethofencarb 3,5-DIETHOXYANILINE 2,5-DIETHOXYANILINE 1,2-Diethoxyaniline 4-ACRYLOYLAMIDOBENZO-15-CROWN-5, 99 4'-AMINODIBENZO-18-CROWN-6 METHYL 2-AMINO-4,5-DIETHOXYBENZOATE 2-DODECYL-2-METHYL-1,3-PROPANEDIYL BIS[N-[5'-NITRO(BENZO-15-CROWN-5)-4'-YL]CARBAMATE]

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