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Diglycolic anhydride

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  • CAS:4480-83-5
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  • CAS:4480-83-5
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  • Purity: 99%
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  • Diglycolic anhydride
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  • CAS:4480-83-5
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Diglycolic anhydride Basic information
Product Name:Diglycolic anhydride
Synonyms:DIGLYCOLIC ANHYDRIDE;DIGLYCOLIC ANHYDRIDE, TECH., 90%;Diglycolicanhydride,95%;Acetic acid, 2,2'-oxybis-, cyclic anhydride;Acetic acid, oxydi-, cyclic anhydride;Diglycolic acid anhydride;Oxydiacetic anhydride;p-Dioxane-2,6-dione
CAS:4480-83-5
MF:C4H4O4
MW:116.07
EINECS:224-761-5
Product Categories:Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Dioxanes;Dioxanes & Dioxolanes
Mol File:4480-83-5.mol
Diglycolic anhydride Structure
Diglycolic anhydride Chemical Properties
Melting point 92-93 °C (lit.)
Boiling point 240-241 °C (lit.)
density 1.4230
refractive index 1.5800 (estimate)
Fp 240-241°C
storage temp. Store below +30°C.
solubility Soluble in chloroform.
form Crystalline Powder, Crystals or Needles
color White to pale cream
Sensitive Moisture Sensitive
BRN 112527
Stability:Hygroscopic, Moisture Sensitive
InChIKeyPIYNUZCGMLCXKJ-UHFFFAOYSA-N
CAS DataBase Reference4480-83-5(CAS DataBase Reference)
NIST Chemistry Reference1,4-Dioxane-2,6-dione(4480-83-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25
RIDADR 2923
WGK Germany 3
10-21
HazardClass 8
PackingGroup III
HS Code 29189090
MSDS Information
ProviderLanguage
Diglycolic anhydride English
SigmaAldrich English
ACROS English
ALFA English
Diglycolic anhydride Usage And Synthesis
Chemical Propertieswhite to off-white
UsesDiglycolic anhydride is used in the preparation of N,N-diethyldiglycollamsaeure by reacting with diethylamine. It is an useful bio chemical for proteomics research.
Synthesis 50.01 g of diglycolic acid was dissolved in 140 mL of acetic anhydride, Heated to 145 ℃, Add 5 drops of phosphoric acid as initiator, And the mixture was refluxed for 2 hours. After the reaction was stopped, Most acetic anhydride was removed by rotary evaporation at 80 ℃. Approximately 100 mL of liquid was obtained,300 mL of toluene was added. Stirring, and allowed to stand for 10 hours. Vacuum filtration to give 38.89g colourless to white Diglycolic anhydride crystals. The yield was 90%.
Diglycolic anhydride Preparation Products And Raw materials
Preparation ProductsMORPHOLINE-3 5-DIONE 97
Tag:Diglycolic anhydride(4480-83-5) Related Product Information
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