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| | Hexylamine Basic information |
| Product Name: | Hexylamine | | Synonyms: | гексиламин, гексан-1-амин, 1-аминогексан, hexan-1-amine, n-hexylamine, 1-Aminohexane;Hexan-1-amine, гексиламин, гексан-1-амин, 1-аминогексан, n-hexylamine, 1-Aminohexane;H**n-hexylamine;NORMAL HEXYL AMINE;Hexylamin;hexylamine,[liquid];n-C6H13NH2;aminohexane | | CAS: | 111-26-2 | | MF: | C6H15N | | MW: | 101.19 | | EINECS: | 203-851-8 | | Product Categories: | Fine Chemical;Alkylamines;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes | | Mol File: | 111-26-2.mol |  |
| | Hexylamine Chemical Properties |
| Melting point | −23 °C(lit.) | | Boiling point | 131-132 °C(lit.) | | density | 0.766 g/mL at 25 °C(lit.) | | vapor pressure | 10.6 hPa (20 °C) | | refractive index | n20/D 1.418(lit.) | | FEMA | 4243 | HEXYLAMINE | | Fp | 27 °C | | storage temp. | Store below +30°C. | | solubility | 14g/l | | pka | 10.56(at 25℃) | | form | Liquid | | color | Clear colorless to slightly yellow | | Odor | at 0.10 % in propylene glycol. ammoniacal musty fishy | | PH | 11.6 (10g/l, H2O, 20℃) | | Odor Type | fishy | | explosive limit | 2.1-9.3%(V) | | Water Solubility | 14 g/L (20 ºC) | | Sensitive | Air Sensitive | | JECFA Number | 1588 | | BRN | 1731298 | | Dielectric constant | 4.0800000000000001 | | Stability: | Stable. Incompatible with acids, acid anhydrides, acid chlorides, carbon dioxide, strong oxidizing agents. | | InChI | 1S/C6H15N/c1-2-3-4-5-6-7/h2-7H2,1H3 | | InChIKey | BMVXCPBXGZKUPN-UHFFFAOYSA-N | | SMILES | CCCCCCN | | LogP | 2.06-2.31 at 25℃ | | CAS DataBase Reference | 111-26-2(CAS DataBase Reference) | | NIST Chemistry Reference | 1-Hexanamine(111-26-2) | | EPA Substance Registry System | Hexylamine (111-26-2) |
| Hazard Codes | C,F,Xi,N | | Risk Statements | 10-21/22-35-20/21/22-51/53 | | Safety Statements | 26-36/37/39-45-16-61 | | RIDADR | UN 2734 8/PG 1 | | WGK Germany | 1 | | RTECS | MQ4540000 | | F | 34 | | Autoignition Temperature | 270 °C | | Hazard Note | Irritant/Flammable/Corrosive/Air Sensitive | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29159020 | | HS Code | 29211980 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1A | | Hazardous Substances Data | 111-26-2(Hazardous Substances Data) | | Toxicity | LD50 orally in Rabbit: 240 mg/kg |
| | Hexylamine Usage And Synthesis |
| Chemical Properties | colourless liquid | | Chemical Properties | Colorless to yellow liquid; fishy aroma. | | Chemical Properties | n-Hexylamine is a colorless, flammable liquid, slightly soluble in water
and soluble in alcohol and ether. | | Uses | n-Hexylamine is
used in organic syntheses. | | Uses | 1-Hexylamine is used as corrosion inhibitors, emulsifiers and surfactants. It is used in dyes, rubber and pharmaceutical industries. It is also used to study the modification of alkanethlol monolayers in gas-phase surface reactions. It acts as an initiator in the ring opening polymerization of N-carboxyanhydride. | | Uses | Toxic by ingestion, inhalation, and skin
absorption. Flammable, moderate fire risk. | | Definition | ChEBI: A 6-carbon primary aliphatic amine. | | Aroma threshold values | High strength odor; fishy type, recommend smelling in a 0.10% solution or less | | Synthesis Reference(s) | The Journal of Organic Chemistry, 55, p. 2271, 1990 DOI: 10.1021/jo00295a002
Synthesis, p. 605, 1981 | | General Description | A water-white liquid with an amine-like odor. Flash point 85°F. Boiling point 132°F. Less dense than water and poorly soluble in swater. Hence floats on water. May be toxic by inhalation, ingestion or skin absorption. | | Air & Water Reactions | Highly flammable. Slightly soluble in water. | | Reactivity Profile | HEXYLAMINE neutralize acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | | Health Hazard | Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | | Flammability and Explosibility | Flammable | | Purification Methods | Dry with, and fractionally distil the hexylamine from, KOH or CaH2. Store away from CO2. [Beilstein 4 IV 709.] |
| | Hexylamine Preparation Products And Raw materials |
| Raw materials | Phosphorus pentachloride-->Hexanamide, N-hexyl--->DI-N-HEXYLAMINE-->1H-Isoindole-1,3(2H)-dione, 2-hexyl--->TRI-N-HEXYLAMINE-->1,2-Benzenedimethanol | | Preparation Products | 6-N-HEXYLAMINOPURINE-->Hexyl isocyanate-->5-PyriMidinecarboxylic acid, 4-[1,1'-biphenyl]-4-yl-1-[6-[[2-(butylaMino)-1-[3-(Methoxycarbonyl)-4-(2-Methoxy-2-oxoethoxy)phenyl]-2-oxoethyl]hexylaMino]-6-oxohexyl]-1,2,3,4-tetrahydro-6-Methyl-2-oxo-, phenylMethyl ester-->Triethyl 1,3,5-benzenetricarboxylate-->HEXANAMIDE-->N-METHYLHEXYLAMINE-->N,N-DIMETHYLHEXYLAMINE-->2-BROMOBENZO[B]THIOPHENE-->3-(HEXYLAMINO)PROPIONITRILE |
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